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How many cyclic structures are possible for $$\text{C}_4\text{H}_6$$?
The degree of unsaturation (also called index of hydrogen deficiency, IHD) tells us how many $$\pi$$-bonds and/or rings are present in a hydrocarbon.
For a general hydrocarbon $$C_nH_m$$, $$\text{IHD}= \dfrac{2n+2-m}{2}$$.
For $$C_4H_6$$, $$\text{IHD}= \dfrac{2(4)+2-6}{2}= \dfrac{10-6}{2}=2$$.
Thus every valid structure must contain a total of two units of unsaturation.
Each ring counts as 1 unit and each double bond also counts as 1 unit.
Because the question asks for cyclic structures, at least one ring must be present. Therefore we have two possible patterns of unsaturation:
Case 1: one ring + one double bond.
Case 2: two rings and no double bond (bicyclic system).
Case 1: One ring + one double bond (four-carbon skeleton)
1. Cyclobutene : $$\mathrm{C_4H_6}$$ with the double bond inside the 4-membered ring.
Only one constitutional arrangement is possible because all C atoms of cyclobutene are equivalent.
2. Methyl-substituted cyclopropenes (3-membered ring contains the double bond). a) 1-Methylcyclopropene (methyl on a vinylic carbon, unique because the two vinylic positions are equivalent). b) 3-Methylcyclopropene (methyl on the saturated ring carbon). These two are not identical, so they give two distinct structures.
3. Methylenecyclopropane : a 3-membered ring where the double bond is exocyclic, i.e. $$\mathrm{CH_2{=}C_3}$$ (ring carbon 3 is doubly bonded to an external $$\mathrm{CH_2}$$ group). This satisfies one ring + one double bond and is different from the cyclopropenes above.
Hence, under Case 1 we have 1 (cyclobutene) + 2 (methylcyclopropenes) + 1 (methylenecyclopropane) = 4 distinct cyclic structures.
Case 2: Two rings, no double bond
With four carbons and two rings we need five single C-C bonds (because $$\text{rings} = \text{bonds} - n + 1$$). The unique way to connect four carbon atoms with five single bonds is the “edge-fused” bicyclic skeleton $$\mathrm{bicyclo[1.1.0]butane}$$ (two cyclopropane rings sharing one edge). This gives one additional structure.
Total count
Adding Case 1 (4 structures) and Case 2 (1 structure) gives $$4+1 = 5$$ cyclic structural isomers for $$\mathrm{C_4H_6}$$.
Option B which is: 5
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