Join WhatsApp Icon JEE WhatsApp Group
Question 51

The non-metal that does not exhibit positive oxidation state is:

We begin by recalling the idea of oxidation state. The oxidation state (or oxidation number) of an element in a compound is a hypothetical charge assigned on the basis of a simple set of electron-book-keeping rules. A “positive oxidation state” means the element is treated as if it has lost one or more electrons.

Whether an element can show a positive oxidation state largely depends on its electronegativity. The general rule is:

$$\text{More electronegative element} \; \Rightarrow \; \text{negative oxidation state}$$

and only if an element is less electronegative than the partner bonded to it can it be forced into a positive oxidation state.

Now let us look at each non-metal in the options one by one.

Chlorine (Cl)
Chlorine has high electronegativity, but oxygen and fluorine are still more electronegative than chlorine. Therefore, in compounds such as $$Cl_2O$$, $$ClO_2$$, $$HClO_4$$, chlorine takes positive oxidation numbers $$+1, +4, +7$$ respectively. So chlorine does exhibit positive oxidation states.

Iodine (I)
Iodine is less electronegative than chlorine and bromine, and far less than oxygen and fluorine. Hence, in compounds such as $$I_2O_5$$ or $$HIO_3$$, iodine shows positive oxidation numbers $$+5$$. Therefore iodine can also possess positive oxidation states.

Oxygen (O)
Oxygen is the second most electronegative element, yet fluorine is still more electronegative than oxygen. Consequently, when oxygen is bonded to fluorine, as in $$OF_2$$, we must assign:

$$\text{Oxidation number of F} = -1$$ (because fluorine is the most electronegative and is always $$-1$$)

Using the algebraic sum rule $$\sum (\text{oxidation numbers}) = 0$$ for a neutral molecule, we get

$$2(-1) + (\text{oxidation number of O}) = 0$$

$$\Rightarrow \text{oxidation number of O} = +2$$

Thus oxygen also exhibits a positive oxidation state in $$OF_2$$.

Fluorine (F)
Fluorine is the most electronegative element of all ($$ \chi = 3.98$$ on the Pauling scale). Because no other element outranks fluorine in electronegativity, there is no partner to which fluorine can lose electron density. Therefore, fluorine is always assigned the oxidation number $$-1$$ in all its compounds; it never shows $$+1, +3, +5,$$ or any other positive value.

So among the given non-metals, fluorine uniquely lacks any positive oxidation state.

Hence, the correct answer is Option C.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Atomic StructureJEE Applications of DerivativesJEE Complex NumbersJEE Fluid MechanicsJEE Alcohols, Phenols & EthersJEE Basic Principles of Organic ChemistryJEE Trigonometric FunctionsJEE Three Dimensional GeometryJEE Electromagnetic WavesJEE Redox ReactionsJEE SolutionsJEE Laws of ThermodynamicsJEE Ray OpticsJEE Organic Compounds with HalogensJEE Chemical ThermodynamicsJEE Permutations & CombinationsJEE DeterminantsJEE EMF & Circuit AnalysisJEE Aldehydes & KetonesJEE Atoms & NucleiJEE Dual Nature of Matter & RadiationJEE Electric Charges & FieldsJEE Number SystemJEE Units & MeasurementsJEE Simple Harmonic MotionJEE ElasticityJEE Alternating CurrentsJEE Practical Organic ChemistryJEE Electromagnetic InductionJEE Rotational MotionJEE Hydrocarbons - AlkynesJEE CirclesJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Nitrogen-Containing CompoundsJEE Magnetism & Magnetic MaterialsJEE Basic Concepts in ChemistryJEE Laboratory Experiments - XIJEE Periodic Table & PeriodicityJEE Coordination CompoundsJEE Inverse Trigonometric FunctionsJEE Kinetic Theory of GasesJEE Carboxylic AcidsJEE Hydrocarbons - AlkanesJEE d and f-Block ElementsJEE StatisticsJEE LimitsJEE Laws of MotionJEE Electronic DevicesJEE Continuity & DifferentiabilityJEE Sets, Relations & FunctionsJEE Work, Energy & PowerJEE Straight LinesJEE Surface TensionJEE Vector AlgebraJEE ElectrochemistryJEE Kinematics - 2D MotionJEE Chemical KineticsJEE Magnetic Effects of CurrentJEE Binomial TheoremJEE Definite IntegrationJEE ProbabilityJEE Sequences & SeriesJEE Hydrocarbons - AromaticJEE Chemical Bonding & Molecular StructureJEE Hydrocarbons - AlkenesJEE Quadratic EquationsJEE DifferentiationJEE GravitationJEE JEE 2D GeometryJEE p-Block Elements (Groups 13-18)JEE Wave OpticsJEE BiomoleculesJEE Heat TransferJEE Current & ResistanceJEE MatricesJEE Differential EquationsJEE EquilibriumJEE WavesJEE Indefinite IntegrationJEE Electric Potential & CapacitanceJEE Conic Sections
Ask AI