Join WhatsApp Icon JEE WhatsApp Group
Question 45

This reduction reaction is known as:

image

We need to identify the given organic reduction reaction where benzoyl chloride ($$C_6H_5COCl$$) is converted into benzaldehyde ($$C_6H_5CHO$$).

Statement (A): Rosenmund reduction. The Rosenmund reduction is a hydrogenation process where an acyl chloride is selectively reduced to an aldehyde using hydrogen gas ($$H_2$$) over palladium on barium sulfate ($$Pd\text{-}BaSO_4$$). The barium sulfate acts as a catalyst poison to prevent further reduction of the aldehyde into a primary alcohol. This matches the given reaction perfectly. This is TRUE.

Statement (B): Wolff-Kishner reduction. The Wolff-Kishner reduction is used to convert a carbonyl group (aldehyde or ketone) into a methylene group ($$\text{-}CH_2\text{-}$$) using hydrazine ($$NH_2NH_2$$) and a strong base like $$KOH$$. This is FALSE.

Statement (C): Stephen reduction. The Stephen reduction involves the preparation of aldehydes from nitrites ($$R\text{-}CN$$) using tin(II) chloride ($$SnCl_2$$) and hydrochloric acid ($$HCl$$), followed by hydrolysis. This is FALSE.

Statement (D): Etard reduction. The Etard reduction is a reaction that oxidizes an aromatic methyl group to an aldehyde group using chromyl chloride ($$CrO_2Cl_2$$). This is FALSE.

The given reaction represents the Rosenmund reduction.

Answer: Option A — Rosenmund reduction

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI