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In each sub question below a statement S and an explanation E is given. Choose the correct answer from the codes A, B, C, D, E given below for each question.<br>(A) S is correct but E is incorrect<br>(B) S is incorrect but E is correct<br>(C) Both S and E are correct and E is correct explanation of S<br>(D) Both S and E are correct but E is not correct explanation of S<br>(E) Both S and E are incorrect<br>i) S - The third period contains only 8 elements and not 18 like $$4^{\text{th}}$$ period. E - In III period filling starts from $$3s^1$$ and complete at $$3p^6$$ whereas in IV period it starts from $$4s^1$$ and complete after $$3d^{10}$$ and $$4s^2$$<br>ii) S - Transition elements show horizontal as well as vertical relationship. E - This is due to shielding effect and similar electronic configuration<br>iii) S - Cs and $$\text{F}_2$$ combines violently to form CsF. E - Cs is most electropositive and F is most electronegative<br>iv) S - A jump in $$3^{\text{rd}}$$ ionisation energy is noticed in case of alkaline earth metals. E - The jump in ionisation energy is due to change in major energy shell during successive removal of electron<br>v) S - First ionisation energy of Be is more than that $$\text{IE}_1$$ of B. E - Removal of electron in Be occurs from 2s subshell whereas in B from 2p subshell<br>vi) S - Formation of $$\text{Cl}^-$$ is exothermic whereas formation of $$\text{O}^{2-}$$ endothermic. E - $$\text{EA}_2$$ of oxygen is endothermic and greater than its exothermic value $$\text{EA}_1$$ of oxygen<br>vii) S - $$\text{BiCl}_5$$ does not exist. E - In Bi inert pair effect is more predominant<br>viii) S - Second EA for halogens is zero. E - Fluorine has maximum value of electron affinity
Correct Answer: 0
PLACEHOLDER ANSWER - the answer is eight codes. i) C - period 3 fills only 3s and 3p (8 electrons) because 3d is filled only after 4s, in period 4 (though E's wording of where period 4 ends is loose, since it completes at $$4p^6$$). ii) C - similar outer configurations and the poor shielding by d electrons give transition elements their similarities along periods as well as groups. iii) C - the most electropositive metal and the most electronegative non-metal react violently. iv) C - the third electron of an alkaline earth metal comes from the inner noble-gas shell. v) C - a 2s electron is more penetrating and harder to remove than a 2p electron. vi) C - $$\text{EA}_2$$ of oxygen (about $$+780\text{ kJ mol}^{-1}$$) outweighs its $$\text{EA}_1$$ (about $$-141\text{ kJ mol}^{-1}$$). vii) C - the inert pair effect makes the $$+5$$ state of Bi unstable. viii) E - the second electron gain of halogens is strongly endothermic, not zero, and chlorine (not fluorine) has the highest electron affinity.
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