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While $$Fe^{3+}$$ is stable, $$Mn^{3+}$$ is not stable in acid solution because
$$O_2$$ oxidises $$Mn^{2+}$$ to $$Mn^{3+}$$
$$O_2$$ oxidises both $$Mn^{2+}$$ to $$Mn^{3+}$$ and $$Fe^{2+}$$ to $$Fe^{3+}$$
$$Fe^{3+}$$ oxidises $$H_2O$$ to $$O_2$$
$$Mn^{3+}$$ oxidises $$H_2O$$ to $$O_2$$
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