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Meta Directing Groups:
The groups which direct the incoming group to the meta position are called meta directing groups.
Some examples of meta directing groups are:
-NO₂, -CHO, -COOH, -COOR, -COR, -CN, -SO₃H, -NH₃⁺, -CF₃, etc. So the Cl adds at the Meta Position. The compound B is formed (m-chloronitrobenzene).
The next step is reduction of the nitro group to amine group converting compound B (m-chloronitrobenzene), into compound C, (m-chloroaniline).
Option D corresponds to the right compounds.
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