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$$\text{NH}_4^+$$ ion in aqueous solution will behave as.
$$\text{NH}_4^+$$ is the conjugate acid of the weak base $$\text{NH}_3$$. In water it donates a proton, $$\text{NH}_4^+ + \text{H}_2\text{O} \rightleftharpoons \text{NH}_3 + \text{H}_3\text{O}^+$$, so it behaves as an acid.
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