Join WhatsApp Icon JEE WhatsApp Group
Question 26

The electron of a hydrogen atom makes a transition from the $$(n+1)^{\text{th}}$$ orbit to the $$n^{\text{th}}$$ orbit. For large $$n$$ the wavelength of the emitted radiation is proportional to

Solution

For a hydrogen atom the energy of the electron in the $$n^{\text{th}}$$ Bohr orbit is given by
$$E_n = -\frac{13.6\ \text{eV}}{n^2}$$

The photon emitted when the electron drops from orbit $$n+1$$ to orbit $$n$$ carries an energy equal to the difference between these two levels:

$$\Delta E = \lvert E_{n+1} - E_n \rvert$$

Substituting the Bohr energies,

$$\Delta E = \left| -\frac{13.6}{(n+1)^2} - \left(-\frac{13.6}{n^2}\right) \right| = 13.6 \left[ \frac{1}{n^2} - \frac{1}{(n+1)^2} \right]$$

Simplify the bracket:

$$\frac{1}{n^2} - \frac{1}{(n+1)^2} = \frac{(n+1)^2 - n^2}{n^2(n+1)^2} = \frac{n^2 + 2n + 1 - n^2}{n^2(n+1)^2} = \frac{2n + 1}{n^2(n+1)^2}$$

Hence

$$\Delta E = 13.6 \frac{2n + 1}{n^2(n+1)^2}$$

For large $$n$$ we can drop the +1 terms inside brackets: $$2n+1 \approx 2n$$ and $$(n+1)^2 \approx n^2$$. Therefore

$$\Delta E \approx 13.6 \frac{2n}{n^4} = \frac{27.2}{n^3}$$

The emitted photon's wavelength $$\lambda$$ is related to its energy by $$\Delta E = \frac{hc}{\lambda}$$, so

$$\lambda = \frac{hc}{\Delta E} \propto \frac{1}{\Delta E} \propto n^3$$

Thus, for large $$n$$ the wavelength varies directly as $$n^3$$.

Option B which is: $$n^3$$

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests
Ask AI