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Calamine, malachite, magnetite and cryolite, respectively, are
$$ZnSO_4, CuCO_3, Fe_2O_3, AlF_3$$
$$ZnSO_4, Cu(OH)_2, Fe_30_4,, Na_3AlF_6$$
$$ZnCO_3, CuCO_3.Cu(OH)_2, Fe_3O_4, Na_3AlF_6$$
$$ZnCO_3, CuCO_3, Fe_2O_3, Na_3AlF_6$$
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