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Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as
Cyclohexanone is a ketone; dimethylamine, $$\left(CH_3\right)_2NH$$, is a secondary amine.
General carbonyl-amine condensations proceed as follows:
• With a primary amine ($$RNH_2$$) the carbonyl first gives a carbinolamine, then—after elimination of water—an $$C{=}\!N$$ double bond (imine/Schiff base) is produced.
• With a secondary amine ($$R_2NH$$) the carbinolamine formed initially cannot lose a second N-H proton (none is present). Instead, it eliminates the α-hydrogen of the carbonyl compound, giving a C=C-N skeleton known as an enamine.
The overall transformation for cyclohexanone is:
$$\text{cyclohexanone} + \left(CH_3\right)_2NH \;\xrightarrow[\text{-H}_2\text{O}]{\text{acid cat.}}\; \text{enamine} + H_2O$$
Continuous removal of water shifts the equilibrium to the product side (Le Chatelier’s principle) and ensures good yield of the enamine.
Thus the compound obtained is an enamine.
Option B which is: an enamine
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