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NTA JEE Main 27th July 2022 Shift 1 - Chemistry

For the following questions answer them individually

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A:
Energy of $$2s$$ orbital of hydrogen atom is greater than that of $$2s$$ orbital of lithium.
Reason R: Energies of the orbitals in the same subshell decrease with increase in the atomic number.
In the light of the above statements, choose the correct answer from the options given below

The incorrect statement is

Given below are two statements.

Statement I: $$O_2$$, $$Cu^{2+}$$ and $$Fe^{3+}$$ are weakly attracted by magnetic field and are magnetized in the same direction as magnetic field.
Statement II: $$NaCl$$ and $$H_2O$$ are weakly magnetized in opposite direction to magnetic field.
In the light of the above statements, choose the most appropriate answer form the options given below

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A:
Activated charcoal adsorbs $$SO_2$$ more efficiently than $$CH_4$$.
Reason R: Gases with lower critical temperatures are readily adsorbed by activated charcoal.
In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements:

Statement I: Hydrogen peroxide can act as an oxidizing agent in both acidic and basic conditions.
Statement II: Density of hydrogen peroxide at $$298 \text{ K}$$ is lower than that of $$D_2O$$.
In the light of the above statements. Choose the correct answer from the options

Given below are two statements
Statement I:
The chlorides of Be and Al have Cl-bridged structure. Both are soluble in organic solvents and act as Lewis bases.
Statement II: Hydroxides of Be and Al dissolve in excess alkali to give beryllate and aluminate ions.
In the light of the above statements. Choose the correct answer from the options

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A:
[6] Annulene, [8] Annulene and cis-[10] Annulene are respectively aromatic, not-aromatic and aromatic.

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Reason R: Planarity is one of the requirements of aromatic systems.
In the light of the above statements, choose the most appropriate answer from the options given below.

In Carius method of estimation of halogen, $$0.45 \text{ g}$$ of an organic compound gave $$0.36 \text{ g}$$ of $$AgBr$$. Find out the percentage of bromine in the compound. (Molar masses: $$AgBr = 188 \text{ g mol}^{-1}; Br = 80 \text{ g mol}^{-1}$$)

Which of the following methods are not used to refine any metal?
(A) Liquation
(B) Calcination
(C) Electrolysis
(D) Leaching
(E) Distillation
Choose the correct answer from the options given below

Given below are two statements:
Statement I:
Iron (III) catalyst, acidified $$K_2Cr_2O_7$$ and neutral $$KMnO_4$$ have the ability to oxidise $$I^-$$ to $$I_2$$ independently.
Statement II: Manganate ion is paramagnetic in nature and involves $$p\pi - p\pi$$ bonding.
In the light of the above statements, choose the correct answer from the options.

The molar heat capacity for an ideal gas at constant pressure is $$20.785 \text{ J K}^{-1} \text{ mol}^{-1}$$. The change in internal energy is $$5000 \text{ J}$$ upon heating it from $$300 \text{ K}$$ to $$500 \text{ K}$$. The number of moles of the gas at constant volume is ______ (Given: $$R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}$$)

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At $$310 \text{ K}$$, the solubility of $$CaF_2$$ in water is $$2.34 \times 10^{-3} \text{ g/100 mL}$$. The solubility product of $$CaF_2$$ is ______ $$\times 10^{-8} (\text{mol/L})^3$$ (nearest integer). (Given molar mass: $$CaF_2 = 78 \text{ g mol}^{-1}$$)

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