The correct structure of ethylenedianlinetetraacetic acid (EDTA) is
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The correct structure of ethylenedianlinetetraacetic acid (EDTA) is
The ionization ísomer of $$[Cr(H_{2}O)_{4}Cl(NO_{2})]Cl$$ is
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The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The bromoalkane and alkyne respectively are
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The correct statement about the following disaccharide is

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Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows Arrhenius equation is
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The species which by definition has ZERO standard molar enthalpy of formation at 298 K is
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The bond energy (in kcal $$mol^{-1}$$) of a C-C single bond is approximately
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The reagent(s) used for softening the temporary hardness of water is(are)
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In the Newman projection for 2-2 dimethylbutane

X and Y can respectively be
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Among the following, the intensive property is (properties are)
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Aqueous solutions of $$HNO_{3}, KOH, CH_{3}COOH$$ and $$CH_{3}COONa$$ of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)
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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copperinclude chalcanthite $$(CuSo_{4}.5H_{2}O)$$, atacamite $$(Cu_{2}Cl(OH)_{3})$$, cuprite $$Cu_{2}O$$, Copper glance $$Cu_{2}S$$ and malachite $$(Cu_{2}(OH)_{2}CO_{3})$$. However, 80% of the world copper production comes from the ore chalcopyrite $$(CuFeS_{2})$$. The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
Partial roasting of chalcopyrite produces
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Iron is removed from chalcopyrite as
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In self-reduction, the reducing species is
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The concentration of potassiumions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is:
$$M(s)\mid M^{+}(aq; 0.05 molar)\mid \mid M^{+}(aq; 1 molar)\mid M(s)$$
For the above electrolytic cell the magnitude of the cell potential $$\mid E_{cell}\mid=70 mV$$.
For the above cell
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If the 0.05 molar solution of $$M^{+}$$ is replaced by a 0.0025 molar $$M^{+}$$ solution, then the magnitude of the cell potential would be
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The total number of basic groups in the following form of lysine is

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The total numberof cyclic isomers possible for a hydrocarbon with the molecular formula $$C_{4}H_{6}$$ is
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In the scheme given below, the total number of intramolecular aldol condensation products form 'Y' is

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Amongst the following, the total number of compounds soluble in aqueous $$NaOH$$ is

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Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue is

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Based on VSEPR theory, the number of 90 degree F-Br-F angles in $$BrF_{5}$$ is
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The value of n in the molecular formula $$Be_{n}Al_{2}Si_{6}O_{18}$$ is
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A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL, and 25.0 mL. The numberof significant figures in the average titre value is
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The concentration of R in the reaction $$R\rightarrow P$$ was measured as a function of time and the following data is obtained:

The order of the reaction is
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The number of neutrons emitted when $$_{92}^{235}U$$ undergoes controlled nuclear fission to $$_{54}^{142}Xe$$ and $$_{38}^{90}Sr$$ is
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If the angles A, B andC of a triangle are in an arithmetic progression andif a, b and c denote the lengths of the sides opposite to A, B andC respectively, then the value of the expression $$\frac{a}{c}\sin 2C+\frac{c}{a}\sin 2A$$ is
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Equation of the plane containing the straight line $$\frac{X}{2}=\frac{Y}{3}=\frac{Z}{4}$$ and perpendicular to the plane containing the straight lines $$\frac{X}{3}=\frac{Y}{4}=\frac{Z}{2}$$ and $$\frac{X}{4}=\frac{Y}{2}=\frac{Z}{3}$$ is
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Let $$\omega$$ be a complex cube root of unity with $$\omega\neq1$$. A fair die is thrownthree times. If $$r_{1},r_{2}$$ and $$r_{3}$$ are the numbers obtained on the die, then the probability that is $$\omega^{r_{1}}+\omega^{r_{2}}+\omega^{r_{3}}=0$$
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Let P, Q, R and S be the points on the plane with position vectors $$-2\hat{i}-\hat{j},4\hat{i},3\hat{i}+3\hat{j}$$ and $$-3\hat{i}+2\hat{j}$$ respectively. The quadrilateral PQRS must be a
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The number of $$3\times3$$ matrices A whose entries are either O or 1 and for which the system $$A\begin{bmatrix}x\\y\\z\end{bmatrix}=\begin{bmatrix}1\\0\\0\end{bmatrix}$$ has exactly two distinct solutions, is
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The value of $$\lim_{x \rightarrow 0}\frac{1}{x^{3}}\int_{0}^{x} \frac{t \ln(1+t)}{t^{4}+4}dt$$ is
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Let p and q be real numbers such that $$p\neq 0,p^{3}\neq q$$ and $$p^{3}\neq -q$$. If $$\alpha$$ and $$\beta$$ are nonzero complex numbers satisfying $$\alpha+\beta=-p$$ and $$\alpha^{3}+\beta^{3}=q$$, then a quadratic equation having $$\frac{\alpha}{\beta}$$ and $$\frac{\beta}{\alpha}$$ as its roots is
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Let f, g and h be real-valued functions defined on the interval [0,1] by $$f(x) = e^{x^2} + e^{-x^2}, g(x) = xe^{x^2} + e^{-x^2}$$ and $$h(x) = x^2 e^{x^2} + e^{-x^2}$$. If a, b and c denote, respectively, the absolute maximum of f, g and h on [0, 1], Then
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Let A and B be two distinct points on the parabola $$y^2 = 4x$$. If the axis of the parabola touches a circle of radius r having AB as its diameter, then the slope of the line joining A and B can be
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Let ABC be a triangle such that $$\angle ACB = \frac{\pi}{6}$$ and let a, b and c denote the lengths of the sides opposite to A, B and C respectively. The value(s) of x for which $$a = x^2 + x + 1, b = x^2 - 1$$ and $$c = 2x + 1$$ is (are)
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Let $$z_1$$ and $$z_2$$ be two district complex numbers and let $$z = (1 - t)z_1 + tz_2$$ for some real number t with 0 < t 1. If Arg(w) denotes the principal argument of a nonzero complex number w, then
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Let f be a real-valued function defined on the interval $$(0, \infty)$$ by $$f(x) = \ln x + \int_{0}^{x}\sqrt{1 + \sin t}$$ dt. Then which of the following statement(s) is (are) true ?
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The value(s) of $$\int_{0}^{1}\frac{x^4(1-x)^4}{1+x^2}dx $$ is(are)
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Let p be an odd prime number and $$T_p$$ be the following set of $$2 \times 2$$ matrices:
$$T_p = \left\{A = \begin{bmatrix}a & b \\c & a \end{bmatrix}:a, b, c \in \left\{0, 1, 2, ...., p-1\right\}\right\}$$
The number of A in $$T_p$$, such that A is either symmetric or skew-symmetric or both, and det (A) divisible by p is
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The number of A in $$T_p$$, suchthat the trace of A is not divisible by p but det (A) is divisible by p is
[Note : The trace of a matrix is the sumofits diagonal entries.]
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The number of A in $$T_p$$, such that det (A) is not divisible byp is
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The circle $$x^2 + y^2 - 8x = 0$$ and hyperbola $$\frac{x^2}{9} - \frac{y^2}{4} = 1$$ intersect at the points A and B.
Equation of a common tangent with positive slope to the circle as well as to the hyperbola is
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Equation of the circle with AB as its diameter is
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The numberof values of $$\theta$$ in the interval $$\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)$$ such that $$\theta \neq \frac{n \pi}{5}$$ for $$n = 0, \pm 1, \pm 2$$ and $$\tan \theta = \cot 5 \theta$$ as well as $$\sin 2 \theta = \cos 4 \theta$$ is
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The maximum value of the expression $$\frac{1}{\sin^2 \theta + 3 \sin \theta \cos \theta + 5 \cos^2 \theta}$$ is
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If $$\overrightarrow{a}$$ and $$\overrightarrow{b}$$ are vectors in space given by $$\overrightarrow{a} = \frac{\hat{i} - 2 \hat{j}}{\sqrt{5}}$$ and $$\overrightarrow{b} = \frac{2\hat{i} + \hat{j} + 3\hat{k}}{\sqrt{14}}$$, then the value of $$\left(2\overrightarrow{a} + \overrightarrow{b}\right).\left[\left(\overrightarrow{a} \times \overrightarrow{b}\right) \times \left(\overrightarrow{a} - 2\overrightarrow{b}\right)\right]$$ is
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The line 2x + y = 1 is tangent to the hyperbola $$\frac{x^2}{a^2} - \frac{y^2}{b^2} = 1$$. If this line passes through the point of intersection of the nearest directrix and the x-axis, then the eccentricity of the hyperbola is
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If the distance between the plane $$Ax - 2y + z = d$$ and the plane containing the lines $$\frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$$ and $$\frac{x-2}{3} = \frac{y-3}{4} = \frac{z-4}{5}$$ is $$\sqrt{6}$$, then $$\mid d \mid$$ is
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For any real numberx, let [x] denote the largest integer less than or equal to x. Let f be a real valued function defined on the interval [-10, 10] by
$$f(x) = \begin{cases}x-[x] & if & [x] & is & odd,\\1+[x]-x & if & [x] & is & even\end{cases}$$
Then the value of $$\frac{\pi^2}{10}\int_{-10}^{10}f(x) \cos \pi x dx$$ is
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Let $$\omega$$ be the complex number $$\cos \frac{2 \pi}{3} + i \sin \frac{2 \pi}{3}$$. Then the number of distinct complex numbers z satisfying

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Let $$S_k = 1, 2, .... 100$$, denote the sumof the infinite geometric series whose first term is $$\frac{k-1}{k!}$$ and the common ratio is $$\frac{1}{k}$$. Then the value of $$\frac{100^2}{100!}+\sum_{k=1}^{100}\mid (k^2 - 3k + 1)S_k \mid$$ is
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The number of all possible values of $$\theta$$ , where $$0 < \theta < \pi$$. for which the system of equations
$$(y + z) \cos 3 \theta = (xyz) \sin 3\theta$$
$$x \sin 3 \theta = \frac{2 \cos 3\theta}{y} + \frac{2 \sin 3\theta}{z}$$
$$(xyz) \sin 3\theta = (y + 2z) \cos 3 \theta + y \sin 3 \theta$$
have a solution $$(x_0, y_0, z_0)$$ with $$y_0z_0 \leq 0$$, is
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Let f be a real-valued differentiable function on R (the set of all real numbers) such that f(1) = 1. If the y-intercept of the tangent at any point P(x, y) on the curve y= f(x) is equal to the cube of the abscissa of P, then the value off(-3) is equal to
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Consider a thin square sheet of side L and thickness t, made of a material of resistivity $$\rho$$. The resistance between two opposite faces, shown by the shaded areas in the figure is

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A real gas behaves like an ideal gas if its
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Incandescent bulbs are designed by keeping in mind that the resistance of their filament increases with the increase in temperature. If at room temperature. 100 W, 60 Wand 40 Wbulbs have filament resistances $$R_{100}, R_{60}$$ and $$R_{40}$$, respectively, the relation between these resistances is
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To verify Ohm's law, a student is provided with a test resistor $$R_{T}$$, a high resistance $$R_1$$, a small resistance $$R_2$$, two identical galvanometers $$G_1$$ and $$G_2$$, and a variable voltage source V. The correct circuit to carry out the experiment is
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An AC voltage source of variable angular frequency $$\omega$$ and fixed amplitude $$V_0$$ is connected in series with a capacitance C and anelectric bulb of resistance R (inductance zero). When $$\omega$$ is increased
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A thin flexible wire of length L is connected to two adjacent fixed points and carries a current I in the clockwise direction, as shown in the figure. When the system is put in a uniform magnetic field of strength B going into the plane of the paper, the wire takes the shape of a circle. The tension in the wire is

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A block of mass m is on an inclined plane of angle $$\theta$$. The coefficient of friction between the block and the plane is $$\mu$$ and $$\tan \theta > \mu$$. The block is held stationary by applying a force P parallel to the plane. The direction of force pointing up the plane is taken to be positive. As P is varied from $$P_1 = mg(\sin \theta - \mu \cos \theta)$$ to $$P_2 = mg(\sin \theta + \mu \cos \theta)$$, the frictional force f versus P graph will look like

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A thin uniform annular disc (see figure) of mass M has outer radius 4R and inner radius 3R. The work required to take a unit mass from point P on its axis to infinity is

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A few electric field lines for a system of two charges $$Q_1$$ and $$Q_2$$ fixed at two different points on the x-axis are shown in the figure. These lines suggest that

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A student uses a simple pendulumof exactly 1m length to determine g, the acceleration due to gravity. He uses a stop watch with the least count of 1 sec for this and records 40 secondsfor 20 oscillations. For this observation, which of the following statement(s) is (are) true ?
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A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After their collision, the 1 kg mass reverses its direction and moves with a speed of 2 $$ms^{-1}$$.
Which of the following statement(s) is (are) correct for the system of these two masses ?
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A ray OP of monochromatic light is incident on the face AB of prism ABCD near vertex B at an incident angle of $$60^\circ$$ (see figure). If the refractive index of the material of the prism is $$\sqrt{3}$$, which of the following is (are) correct ?

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One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as shown in the figure. Its pressure at A is $$P_0$$. Choose the correct option(s) from the following

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When a particle of mass m moves on the x-axis in a potential of the form $$V(x) = kx^2$$, it performs simple harmonic motion. The corresponding time period is proportional to $$\sqrt{\frac{m}{k}}$$, as can be seen easily using dimensional analysis. However, the motion of a particle can be periodic even whenits potential energy increases on both sides of x = O in a way different from $$kx^2$$ and its total energy is such that the particle does not escape to infinity. Consider a particle of mass m moving on the x-axis. Its potential energy is $$V(x) = \alpha x^4 (\alpha > 0)$$ for $$\mid x \mid$$ near the origin and becomes a constant equal to $$V_0$$ for $$\mid x \mid \geq X_0$$ (see figure).
If the total energy of the particle is E, it will perform periodic motion only if
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For periodic motion of small amplitude A, the time period T of this particle is proportional to
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The acceleration of this particle for $$\mid x \mid > X_0$$ is
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Electrical resistance of certain materials, known as superconductors, changes abruptly from a nonzero value to zero as their temperature is lowered below a critical temperature $$T_c(0)$$. An interesting property of superconductors is that their critical temperature becomes smaller than $$T_c(0)$$ if they are placed in a magnetic field, i.e., the critical temperature $$T_c(B)$$ is a function of the magnetic field strength B. The dependence of $$T_c(B)$$ on B is shown in the figure.
In the graphs below, the resistance R of a super conductor is shown as a function of its temperature T for two different magnetic fields $$B_1$$ (solid line) and $$B_2$$ (dashed line). If $$B_2$$ is larger than $$B_1$$, which of the following graphs shows the correct variation of R with T in these fields ?
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A superconductor has $$T_c (0) = 100 K$$. When a magnetic field of 7.5 Tesla is applied, its $$T_c$$ decreases to 75 K. For this material one candefinitely say that when
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The focal length of a thin biconvex lens is 20cm. When anobject is moved from a distance of 25cmin front of it to 50cm, the magnification of its image changes from $$m_{25}$$ to $$m_{50}$$. The ratio $$\frac{m_{25}}{m_{50}}$$ is
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An $$\alpha$$-particle and a proton are accelerated from rest by a potential difference of 100V. After this, their de Broglie wavelengths are $$\lambda_{\alpha}$$ and $$\lambda_{p}$$ respectively. The ratio $$\frac{\lambda_p}{\lambda_{\alpha}$$, to the nearest integer, is
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When two identical batteries of internal resistance 1 Ω each are connected in series across a resistor R, the rate of heat produced in R is $$J_1$$. When the samebatteries are connected in parallel across R, the rate is $$J_2$$. If $$J_1 = 2.25 J_2$$ then the value of R in Ω is
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Two spherical bodies A (radius 6 cm) and B (radius 18 cm) are at temperatures $$T_1$$ and $$T_2$$, respectively. The maximum intensity in the emission spectrum of A is at 500 nm and in that of B is at 1500 nm. Considering themto be black bodies, what will be the ratio of the rate of total energy radiated by A to that of B ?
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When two progressive waves $$y_1 = 4 \sin(2x - 6t)$$ and $$y_2 = 3 \sin\left(2x - 6t - \frac{\pi}{2}\right)$$ are superimposed, the amplitude of the resultant wave is
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A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m and its cross-sectional area is $$4.9 \times 10^{-7} m^2$$. If the mass is pulled a little in
the vertically downward direction and released, it performs simple harmonic motion of angular frequency 140 rad $$s^{-1}$$. If the Young’s modulus of the material of the wire is $$n \times 10^9 Nm^{-2}$$, the value of n is
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A binarystar consists of two stars A (mass 2.2 $$M_s$$) and B (mass 11 $$M_s$$). where $$M_s$$ is the mass of the sun. They are separated by distance d and are rotating about their centre of mass, which is stationary. The ratio of the total angular momentum of the binarystar to the angular momentumof star B about the centre of mass is
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Gravitational acceleration on the surface of a planet is $$\frac{\sqrt{6}}{11} g$$, where g is the gravitational acceleration on the surface of the earth. The average mass density of the planet is $$\frac{2}{3}$$ times that of the earth. If the escape speed on the surface of the earth is taken to be 11 $$kms^{-1}$$, the escape speed on the surface of the planet in $$kms^{-1}$$ will be
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A piece of ice (heat capacity = 2100 J $$kg^{-1} {^\circ}C^{-1}$$ andlatent heat = $$3.36 \times 10^5 J kg^{-1}$$) of mass m grams is at $$-5 ^\circ C$$ at atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 gmof ice has melted. Assuming there is no other heat exchange in the process, the value of m is
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A stationary source is emitting sound ata fixed frequency $$f_0$$, which is reflected by two cars approaching the source. The difference between the frequencies of sound reflected from the cars is 1.2% of $$f_0$$. What is the difference in the speeds of the cars (in km per hour) to the nearest integer ? The cars are moving at constant speeds much smaller than the speed of sound which is 330 $$ms^{-1}$$.
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