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Question 54

The major product obtained in the following reaction is:

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  1. Enolate Formation:

    The ethoxide ion ($$\text{OEt}^\ominus$$) abstracts a highly acidic proton from the active methylene carbon located alpha ($$\alpha$$) to both the ester and internal ketone carbonyl groups, generating a resonance-stabilized carbanion as shown in the initial step.


  2. Intramolecular Nucleophilic Attack:

    This carbanion acts as a nucleophile, performing an intramolecular attack directly on the carbonyl carbon of the cyclopentanone ring. This nucleophilic addition effectively closes the chain to create a fused bicyclic system containing a stable, newly formed six-membered ring structure.

Conclusion:

The base-driven enolate generation facilitates a clean ring-closure (intramolecular aldol/condensation pathway) to yield the corresponding bicyclic derivative.

Answer: Option A

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