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Question 35

Match items of column I and II

image

  • A. $$\text{H}_2\text{O} \ / \ \text{CH}_2\text{Cl}_2$$
    • Analysis: Water ($$\text{H}_2\text{O}$$) and dichloromethane ($$\text{CH}_2\text{Cl}_2$$) are immiscible liquids that form two distinct layers due to their differing densities and polarities.
    • Technique: They are separated using a separating funnel via Differential solvent extraction (or simple liquid-liquid extraction).
    • Match: A $$\rightarrow$$ (ii)
  • B. Organic Mixture ($$\alpha$$-tetralone / $$p$$-nitrophenol)
    • Analysis: The image shows two structurally distinct organic compounds (a ketone and a substituted phenol) with different polarities and adsorption tendencies.
    • Technique: Stationary phases like silica gel absorb these components differently, making Column chromatography the ideal method to separate them.
    • Match: B $$\rightarrow$$ (iii)
  • C. Kerosene / Naphthalene
    • Analysis: Kerosene is a mixture of liquid hydrocarbons, while naphthalene is a volatile solid compound. Alternatively, mixtures of liquids with sufficient differences in boiling points or components that can be fractionated are separated by distillation.
    • Technique: Fractional Distillation is used here to separate them based on boiling point differences.
    • Match: C $$\rightarrow$$ (iv)
  • D. $$\text{C}_6\text{H}_{12}\text{O}_6 \ / \ \text{NaCl}$$
    • Analysis: Glucose ($$\text{C}_6\text{H}_{12}\text{O}_6$$) and sodium chloride ($$\text{NaCl}$$) have vastly different solubilities in hot versus cold solvents (like alcohol/water mixtures).
    • Technique: They can be separated cleanly by Crystallization, where one component forms crystals out of the solution while the other remains dissolved.
    • Match: D $$\rightarrow$$ (i)

    Hence,

  • A - (ii), B - (iii), C - (iv), D - (i)

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