Join WhatsApp Icon JEE WhatsApp Group
Question 32

The IUPAC name of the following compound is:

To determine the correct IUPAC name of the given compound, we follow the standard IUPAC nomenclature rules for substituted aromatic compounds.

The molecule contains a benzene ring substituted with four functional groups:

  • $$-CHO$$ (aldehyde)
  • $$-CH_2OH$$ (hydroxymethyl)
  • $$-NH_2$$ (amino)
  • $$-NO_2$$ (nitro)

Among these, the aldehyde group has the highest priority according to IUPAC nomenclature rules:

$$\text{Aldehyde} > \text{Alcohol} > \text{Amine} > \text{Nitro}.$$

Therefore, the aldehyde group is selected as the principal functional group, and the parent compound is benzaldehyde.

The carbon atom attached to the $$-CHO$$ group is assigned position $$1$$. The ring can then be numbered in either direction to obtain the lowest possible set of locants for the remaining substituents.

If numbered clockwise, the substituent positions are

$${3,,4,,6}.$$

If numbered counterclockwise, the substituent positions are

$${2,,4,,5}.$$

According to the lowest set of locants rule, the set

$${2,,4,,5}$$

is preferred because it gives the lower number at the first point of difference.

Thus, the substituent positions are:

  • $$C1$$ : $$-CHO$$
  • $$C2$$ : $$-NO_2$$ (nitro)
  • $$C4$$ : $$-CH_2OH$$ (hydroxymethyl)
  • $$C5$$ : $$-NH_2$$ (amino)

The substituent prefixes are then arranged alphabetically:

  • Amino
  • Hydroxymethyl
  • Nitro

Combining the substituents with their locants and the parent name gives the IUPAC name:

5-amino-4-hydroxymethyl-2-nitrobenzaldehyde.

Hence, the correct answer is

$$\boxed{\text{5-amino-4-hydroxymethyl-2-nitrobenzaldehyde}}.$$

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI