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NTA JEE Mains 24th january 2023 Shift 1 - Chemistry

For the following questions answer them individually

It is observed that characteristic X-ray spectra of elements show regularity. When frequency to the power 'n' i.e. $$\nu^n$$ of X-rays emitted is plotted against atomic number Z, the following graph is obtained.

image


The value of 'n' is

In the depression of freezing point experiment
A. Vapour pressure of the solution is less than that of pure solvent
B. Vapour pressure of the solution is more than that of pure solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point

Statement I: For colloidal particles, the values of colligative properties are of small order as compared to values shown by true solutions at same concentration.
Statement II: For colloidal particles, the potential difference between the fixed layer and the diffused layer of same charges is called the electrokinetic potential or zeta potential.
In the light of the above statements, choose the correct answer from the options given below.

Assertion A: Hydrolysis of an alkyl chloride is a slow reaction but in the presence of NaI, the rate of hydrolysis increases.
Reason R: $$I^-$$ is a good nucleophile as well as a good leaving group.
In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements :
Statement I : Noradrenaline is a neurotransmitter.
Statement II : Low level of noradrenaline is not the cause of depression in human.
In the light of the above statements, choose the correct answer from the options given below

When $$Fe_{0.93}O$$ is heated in presence of oxygen, it converts to $$Fe_2O_3$$. The number of correct statement/s from the following is ______.
A. The equivalent weight of $$Fe_{0.93}O$$ is $$\frac{\text{Molecular weight}}{0.79}$$
B. The number of moles of $$Fe^{2+}$$ and $$Fe^{3+}$$ in 1 mole of $$Fe_{0.93}O$$ is 0.79 and 0.14 respectively.
C. $$Fe_{0.93}O$$ is metal deficient with lattice comprising of cubic closed packed arrangement of $$O^{2-}$$ ions.
D. The % composition of $$Fe^{2+}$$ and $$Fe^{3+}$$ in $$Fe_{0.93}O$$ is 85% and 15% respectively.

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At 298 K, a 1 litre solution containing 10 mmol of $$Cr_2O_7^{2-}$$ and 100 mmol of $$Cr^{3+}$$ shows a pH of 3.0. Given : $$Cr_2O_7^{2-} \to Cr^{3+}$$; $$E^0 = 1.330$$ V and $$\frac{2.303RT}{F} = 0.059$$ V. The potential for the half cell reaction is $$x \times 10^{-3}$$ V. The value of x is _____.

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The number of correct statement/s from the following is _____.
A. Larger the activation energy, smaller is the value of the rate constant.
B. The higher is the activation energy, higher is the value of the temperature coefficient.
C. At lower temperatures, increase in temperature causes more change in the value of k than at higher temperature.
D. A plot of $$\ln k$$ vs $$\frac{1}{T}$$ is a straight line with slope equal to $$-\frac{E_a}{R}$$

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