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NTA JEE Mains 1st Feb 2024 Shift 2 - Chemistry

For the following questions answer them individually

Given below are two statements:
Statement (I): Both metal and non-metal exist in p and d-block elements.
Statement (II): Non-metals have higher ionisation enthalpy and higher electronegativity than the metals.
In the light of the above statements, choose the most appropriate answer from the options given below:

Given below are two statements:
Statement (I): A $$\pi$$ bonding MO has lower electron density above and below the inter-nuclear axis.
Statement (II): The $$\pi^*$$ antibonding MO has a node between the nuclei.
In light of the above statements, choose the most appropriate answer from the options given below:

Match List - I with List - II.

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Choose the correct answer from the options given below:

Given below are two statements:
Statement (I): $$SiO_2$$ and $$GeO_2$$ are acidic while SnO and PbO are amphoteric in nature.
Statement (II): Allotropic forms of carbon are due to property of catenation and $$p\pi - d\pi$$ bond formation.
In the light of the above statements, choose the most appropriate answer from the options given below:

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: In aqueous solutions $$Cr^{2+}$$ is reducing while $$Mn^{3+}$$ is oxidising in nature.
Reason R: Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration.
In the light of the above statement, choose the most appropriate answer from the options given below:

Given below are two statements:
Statement (I): Dimethyl glyoxime forms a six membered covalent chelate when treated with $$NiCl_2$$ solution in presence of $$NH_4OH$$.
Statement (II): Prussian blue precipitate contains iron both in +2 and +3 oxidation states.
In the light of the above statements, choose the most appropriate answer from the options given below:

Consider the following redox reaction: $$MnO_4^- + H^+ + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$$
The standard reduction potentials are given as below:
$$E^0_{MnO_4^-/Mn^{2+}} = +1.51$$ V; $$E^0_{CO_2/H_2C_2O_4} = -0.49$$ V
If the equilibrium constant of the above reaction is given as $$K_{eq} = 10^x$$, then the value of $$x$$ = ______ (nearest integer)

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