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The values of pressure equilibrium constant recorded at different temperatures for the following equilibrium reaction have been given below
$$A(g) \rightleftharpoons B(g) + C(g)$$
The magnitude of $$\frac{\Delta H^\circ}{R}$$ calculated from the above data is _______. (Nearest integer)
Correct Answer: 230
To find the magnitude of $$\ \frac{\triangle\ H^{\circ\ }}{R}$$, we use the integrated form of the van 't Hoff equation:
$$\log_{10}K_p=-\frac{\triangle H^{\circ\ }}{2.303RT}\ +$$ Constant
Step 1: Identify the slope
The equation is in the form of $$y=mx+c$$,
where:
$$y=\log_{10}K_p$$
$$x=\frac{1}{T}$$
$$m\left(slope\right)=-\frac{\triangle H^{\circ\ }}{2.303R}\ $$
Using the first two points from the table:
$$\left(x_1,y_1\right)=\left(0.05,3.5\right)$$
$$\left(x_2,y_2\right)=\left(0.06,2.5\right)$$
Therefore,
$$slope\left(m\right)=\frac{y_2-y_1}{x_2-x_1}=\frac{2.5-3.5}{0.06-0.05}=-\frac{0.1}{0.01}=-100$$
Step 2: Calculate $$\ \frac{\triangle\ H^{\circ\ }}{R}$$
Equating the calculated slop $$(m)$$
$$-100=-\frac{\triangle H^{\circ\ }}{2.303R}$$
$$100\times\ 2.303=\frac{\triangle H^{\circ\ }}{R}$$
$$230.3=\frac{\triangle H^{\circ\ }}{R}$$
Therefore, the nearest integer is 230.
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