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Sucrose hydrolyses in acidic medium into glucose and fructose by first order rate law with $$t_{1/2} = 3$$ hour. The percentage of sucrose remaining after 6 hours is _______. (Nearest integer)
(Given: log 2 = 0.3010 and log 3 = 0.4771)
Correct Answer: 25
For a first-order reaction, the half-life remains constant.
The number of half-lives elapsed in $$6\ \text{hours}$$ is
$$n=\frac{t}{t_{1/2}}=\frac{6}{3}=2$$
After the first half-life:
$$100%\rightarrow 50%$$
After the second half-life:
$$50%\rightarrow 25%$$
Alternatively,
$$\text{Amount remaining}=\frac{\text{Initial amount}}{2^n}=\frac{100}{2^2}=25%$$
Therefore, the percentage of sucrose remaining after $$6\ \text{hours}$$ is
$$25%$$
Hence, the correct answer is $$25$$.
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