Sign in
Please select an account to continue using cracku.in
↓ →
Prep with like-minded aspirants; Get access to free daily tests and study material.
In the reaction of potassium dichromate, potassium chloride and sulfuric acid (conc.), the oxidation state of the chromium in the product is +
Correct Answer: 6
In conc. sulfuric acid and potassium chloride, potassium dichromate produces chromyl chloride, $$CrO_2Cl_2$$, which is a neutral molecule containing chromium.
Rule: In any neutral molecule, the sum of oxidation states equals zero. Let the oxidation state of chromium in $$CrO_2Cl_2$$ be $$x$$. Then
$$x + 2\times(\text{ox. state of O}) + 2\times(\text{ox. state of Cl}) = 0\quad-(1)$$
We know: Oxygen has oxidation state $$-2$$ and chlorine has oxidation state $$-1$$. Substituting these into $$(1)$$ gives:
$$x + 2(-2) + 2(-1) = 0\quad-(2)$$
Simplify equation $$(2)$$:
$$x -4 -2 = 0$$
$$x -6 = 0\quad-(3)$$
From $$(3)$$, we get:
$$x = 6$$
Therefore, the oxidation state of chromium in the product $$CrO_2Cl_2$$ is +6.
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.