Join WhatsApp Icon JEE WhatsApp Group
Question 56

The cell potential for $$Zn | Zn^{2+}(aq) || Sn^{x+} | Sn$$ is $$0.801 \text{ V}$$ at $$298 \text{ K}$$. The reaction quotient for the above reaction is $$10^{-2}$$. The number of electrons involved in the given electrochemical cell reaction is ______.
(Given $$E^0_{Zn^{2+}|Zn} = -0.763 \text{ V}$$, $$E^0_{Sn^{x+}|Sn} = +0.008 \text{ V}$$ and $$\dfrac{2.303RT}{F} = 0.06 \text{ V}$$)


Correct Answer: 4

We need to find the number of electrons involved in the electrochemical cell reaction.

The cell is: $$Zn | Zn^{2+}(aq) || Sn^{x+} | Sn$$

Anode (oxidation): $$Zn \rightarrow Zn^{2+} + 2e^-$$

Cathode (reduction): $$Sn^{x+} + xe^- \rightarrow Sn$$

$$E^0_{cell} = E^0_{cathode} - E^0_{anode}$$

$$E^0_{cell} = E^0_{Sn^{x+}|Sn} - E^0_{Zn^{2+}|Zn}$$

$$= 0.008 - (-0.763) = 0.771 \text{ V}$$

$$E_{cell} = E^0_{cell} - \dfrac{0.06}{n} \log Q$$

where n is the number of electrons transferred and Q is the reaction quotient.

$$0.801 = 0.771 - \dfrac{0.06}{n} \log(10^{-2})$$

$$0.801 = 0.771 - \dfrac{0.06}{n} \times (-2)$$

$$0.801 = 0.771 + \dfrac{0.12}{n}$$

$$0.801 - 0.771 = \dfrac{0.12}{n}$$

$$0.03 = \dfrac{0.12}{n}$$

$$n = \dfrac{0.12}{0.03} = 4$$

With $$n = 4$$, the cathode half-reaction is: $$Sn^{4+} + 4e^- \rightarrow Sn$$, so $$x = 4$$.

The overall balanced reaction: $$2Zn + Sn^{4+} \rightarrow 2Zn^{2+} + Sn$$ (4 electrons transferred).

Hence, the answer is 4.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Hydrocarbons - AlkenesJEE SolutionsJEE EquilibriumJEE Chemical Bonding & Molecular StructureJEE Quadratic EquationsJEE Electromagnetic WavesJEE Laws of ThermodynamicsJEE CirclesJEE StatisticsJEE Rotational MotionJEE Periodic Table & PeriodicityJEE BiomoleculesJEE Kinetic Theory of GasesJEE Electric Potential & CapacitanceJEE Laboratory Experiments - XIJEE Differential EquationsJEE Binomial TheoremJEE Carboxylic AcidsJEE Applications of DerivativesJEE Vector AlgebraJEE Alcohols, Phenols & EthersJEE Nitrogen-Containing CompoundsJEE Sets, Relations & FunctionsJEE Electronic DevicesJEE Work, Energy & PowerJEE Definite IntegrationJEE DeterminantsJEE d and f-Block ElementsJEE Complex NumbersJEE MatricesJEE Magnetism & Magnetic MaterialsJEE Number SystemJEE Indefinite IntegrationJEE Permutations & CombinationsJEE Fluid MechanicsJEE Sequences & SeriesJEE Inverse Trigonometric FunctionsJEE Three Dimensional GeometryJEE Aldehydes & KetonesJEE Basic Concepts in ChemistryJEE Alternating CurrentsJEE Kinematics - 2D MotionJEE Current & ResistanceJEE Hydrocarbons - AlkanesJEE Simple Harmonic MotionJEE Dual Nature of Matter & RadiationJEE ElectrochemistryJEE Electric Charges & FieldsJEE Magnetic Effects of CurrentJEE GravitationJEE Heat TransferJEE Atoms & NucleiJEE Redox ReactionsJEE Chemical ThermodynamicsJEE DifferentiationJEE Practical Organic ChemistryJEE Wave OpticsJEE Atomic StructureJEE Units & MeasurementsJEE Trigonometric FunctionsJEE WavesJEE Straight LinesJEE Basic Principles of Organic ChemistryJEE EMF & Circuit AnalysisJEE Hydrocarbons - AromaticJEE ProbabilityJEE Ray OpticsJEE Coordination CompoundsJEE p-Block Elements (Groups 13-18)JEE Organic Compounds with HalogensJEE Electromagnetic InductionJEE Surface TensionJEE Purification & CharacterisationJEE Conic SectionsJEE Continuity & DifferentiabilityJEE JEE 2D GeometryJEE Laws of MotionJEE LimitsJEE Kinematics - 1D MotionJEE Chemical KineticsJEE ElasticityJEE Hydrocarbons - Alkynes
Ask AI