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Question 55

On reaction with stronger oxidizing agent like $$KIO_4$$, hydrogen peroxide oxidizes with the evolution of $$O_2$$. The oxidation number of I in $$KIO_4$$ changes to


Correct Answer: 5

We are told that $$KIO_4$$ (potassium periodate) is a stronger oxidizing agent that reacts with hydrogen peroxide ($$H_2O_2$$), causing $$H_2O_2$$ to get oxidized with the evolution of $$O_2$$. We need to find the oxidation number of iodine in the product after this reaction.

In $$KIO_4$$, potassium has an oxidation state of +1 and each oxygen has -2. So the oxidation state of iodine is: $$+1 + x + 4(-2) = 0$$, which gives $$x = +7$$. So iodine starts with an oxidation state of +7.

The reaction is:

$$KIO_4 + H_2O_2 \rightarrow KIO_3 + H_2O + O_2$$

Here, $$H_2O_2$$ is oxidized (oxygen goes from -1 in $$H_2O_2$$ to 0 in $$O_2$$), while $$KIO_4$$ is reduced. The iodine in $$KIO_4$$ (oxidation state +7) is reduced to iodine in $$KIO_3$$ (potassium iodate).

In $$KIO_3$$: $$+1 + x + 3(-2) = 0$$, which gives $$x = +5$$.

So the oxidation number of iodine changes from +7 in $$KIO_4$$ to +5 in $$KIO_3$$.

Hence, the correct answer is 5.

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