Join WhatsApp Icon JEE WhatsApp Group
Question 54

At 600 K, 2 mol of NO are mixed with 1 mol of $$O_2$$.
$$2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g)$$
The reaction occurring as  comes to equilibrium under a total pressure of 1 atm. Analysis of the system shows that 0.6 mol of oxygen are present at equilibrium. The equilibrium constant for the reaction is _____


Correct Answer: 2

We are given the reaction $$2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g)$$ at 600 K. Initially, 2 mol of NO and 1 mol of $$O_2$$ are mixed, and the total pressure at equilibrium is 1 atm. At equilibrium, 0.6 mol of $$O_2$$ is present. We need to find the equilibrium constant $$K_p$$.

Let us set up an ICE table. Let $$x$$ be the moles of $$O_2$$ consumed.

Since 1 mol of $$O_2$$ was initially present and 0.6 mol remains at equilibrium, $$x = 1 - 0.6 = 0.4$$ mol of $$O_2$$ has been consumed.

From the stoichiometry, 2 mol of NO are consumed for every 1 mol of $$O_2$$, so moles of NO consumed = $$2 \times 0.4 = 0.8$$ mol. Also, 2 mol of $$NO_2$$ are formed for every 1 mol of $$O_2$$ consumed, so moles of $$NO_2$$ formed = $$2 \times 0.4 = 0.8$$ mol.

At equilibrium:

$$n_{NO} = 2 - 0.8 = 1.2 \text{ mol}$$

$$n_{O_2} = 1 - 0.4 = 0.6 \text{ mol}$$

$$n_{NO_2} = 0 + 0.8 = 0.8 \text{ mol}$$

Total moles at equilibrium: $$n_{total} = 1.2 + 0.6 + 0.8 = 2.6 \text{ mol}$$

Now we calculate the mole fractions and partial pressures (using $$P_{total} = 1$$ atm):

$$P_{NO} = \frac{1.2}{2.6} \times 1 = \frac{1.2}{2.6} \text{ atm}$$

$$P_{O_2} = \frac{0.6}{2.6} \times 1 = \frac{0.6}{2.6} \text{ atm}$$

$$P_{NO_2} = \frac{0.8}{2.6} \times 1 = \frac{0.8}{2.6} \text{ atm}$$

The equilibrium constant expression is:

$$K_p = \frac{(P_{NO_2})^2}{(P_{NO})^2 \cdot P_{O_2}}$$

Substituting:

$$K_p = \frac{\left(\frac{0.8}{2.6}\right)^2}{\left(\frac{1.2}{2.6}\right)^2 \times \frac{0.6}{2.6}}$$

$$= \frac{\frac{0.64}{6.76}}{\frac{1.44}{6.76} \times \frac{0.6}{2.6}}$$

$$= \frac{0.64}{1.44 \times \frac{0.6}{2.6}}$$

$$= \frac{0.64 \times 2.6}{1.44 \times 0.6}$$

$$= \frac{1.664}{0.864}$$

$$\approx 1.926$$

Rounding to the nearest integer, $$K_p \approx 2$$.

Hence, the correct answer is 2.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI