Join WhatsApp Icon JEE WhatsApp Group
Question 33

Which of the following structures are aromatic in nature?

image

For a compound to be aromatic, it must fulfill four criteria:

  1. Cyclic: The structure must be a closed ring.
    $$\text{}$$
  2. Planar: All atoms in the ring must be $$sp^2$$ hybridized so the p-orbitals can align.
    $$\text{}$$
  3. Fully Conjugated: There must be a continuous system of alternating double bonds, positive charges, negative charges, or lone pairs around the entire ring.
    $$\text{}$$
  4. Hückel's Electron Count: The conjugated loop must contain $$(4n + 2)\,\pi$$ electrons (where $$n = 0, 1, 2, 3...$$, giving allowed counts of $$2, 6, 10, 14...\,\pi$$ electrons)
  • A (Cyclopentadienyl Anion): Cyclic, planar, fully conjugated. It has 2 double bonds ($$4\pi$$ $$e^-$$) + 1 negative charge lone pair ($$2\pi$$ $$e^-$$) = $$6\pi$$ electrons ($$n=1$$). Aromatic.
    $$\text{}$$
  • B (Tropylium Cation): Cyclic, planar, fully conjugated. It has 3 double bonds ($$6\pi$$ $$e^-$$) + 1 empty p-orbital from the positive charge = $$6\pi$$ electrons ($$n=1$$). Aromatic.
    $$\text{}$$
  • C (Naphthalene): Cyclic, planar, fully conjugated bicyclic system. It has 5 double bonds = $$10\pi$$ electrons ($$n=2$$). Aromatic.
    $$\text{}$$
  • D (Cycloheptatrienyl Anion): It contains 3 double bonds ($$6\pi$$ $$e^-$$) + 1 negative charge lone pair ($$2\pi$$ $$e^-$$) = $$8\pi$$ electrons. This follows the $$4n$$ rule ($$n=2$$), making it Anti-aromatic (non-aromatic in reality as it tubs to lose planarity). Not Aromatic.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI