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Question 33

Heat is supplied to a diatomic gas at constant pressure. Then the ratio of $$\Delta Q : \Delta U : \Delta W$$ is __________.

For an ideal diatomic gas (with only translational + rotational degrees of freedom), the number of degrees of freedom is $$f = 5$$. Therefore

$$C_V = \frac{f}{2}R = \frac{5}{2}R,$$
and

$$C_P = C_V + R = \frac{5}{2}R + R = \frac{7}{2}R.$$

Let the gas contain $$n$$ moles and undergo a small temperature rise $$\Delta T$$ at constant pressure.

Heat supplied at constant pressure:
$$\Delta Q = n C_P \,\Delta T = n \left(\frac{7}{2}R\right)\Delta T.$$

Change in internal energy:
$$\Delta U = n C_V \,\Delta T = n \left(\frac{5}{2}R\right)\Delta T.$$

Work done by the gas (ideal gas, constant pressure):
$$\Delta W = P\,\Delta V = nR \,\Delta T.$$

Taking the ratio $$\Delta Q : \Delta U : \Delta W$$ and cancelling the common factors $$nR\Delta T$$, we get

$$\frac{7}{2} : \frac{5}{2} : 1 \;=\; 7 : 5 : 2.$$

Hence the required ratio is $$7:5:2$$.

Option D which is: $$7:5:2$$

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