Join WhatsApp Icon JEE WhatsApp Group
Question 31

Amongst the following, the linear species is:

To identify the linear species, we apply VSEPR theory by counting the steric number (number of bonding pairs + lone pairs) around the central atom of each molecule.

For $$\text{NO}_2$$: nitrogen is the central atom with 17 total valence electrons (5 from N + 6+6 from two O). After forming two N-O bonds, nitrogen has one unpaired electron remaining. The electron geometry is trigonal planar (steric number 3), and the molecular geometry is bent with a bond angle of about 134°. This is not linear.

For $$\text{Cl}_2\text{O}$$: oxygen is the central atom with 20 valence electrons (7+7 from two Cl + 6 from O). Oxygen forms two single bonds with chlorine and has two lone pairs, giving a steric number of 4. The molecular geometry is bent (similar to water), so this is not linear.

For $$\text{O}_3$$: the central oxygen has 18 valence electrons (6+6+6). After forming bonds with the two terminal oxygens, the central oxygen has one lone pair, giving a steric number of 3. The molecular geometry is bent with a bond angle of about 117°. This is not linear.

For $$\text{N}_3^-$$: this ion has 16 valence electrons (5+5+5 from three N + 1 for the negative charge). The central nitrogen forms two double bonds with the terminal nitrogen atoms and has no lone pairs, giving a steric number of 2. With two bonding regions and zero lone pairs, the geometry is linear with a bond angle of 180°.

Therefore, the linear species is $$\text{N}_3^-$$, which is Option D.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Atomic StructureJEE Applications of DerivativesJEE Complex NumbersJEE Fluid MechanicsJEE Alcohols, Phenols & EthersJEE Basic Principles of Organic ChemistryJEE Trigonometric FunctionsJEE Three Dimensional GeometryJEE Electromagnetic WavesJEE Redox ReactionsJEE SolutionsJEE Laws of ThermodynamicsJEE Ray OpticsJEE Organic Compounds with HalogensJEE Chemical ThermodynamicsJEE Permutations & CombinationsJEE DeterminantsJEE EMF & Circuit AnalysisJEE Aldehydes & KetonesJEE Atoms & NucleiJEE Dual Nature of Matter & RadiationJEE Electric Charges & FieldsJEE Number SystemJEE Units & MeasurementsJEE Simple Harmonic MotionJEE ElasticityJEE Alternating CurrentsJEE Practical Organic ChemistryJEE Electromagnetic InductionJEE Rotational MotionJEE Hydrocarbons - AlkynesJEE CirclesJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Nitrogen-Containing CompoundsJEE Magnetism & Magnetic MaterialsJEE Basic Concepts in ChemistryJEE Laboratory Experiments - XIJEE Periodic Table & PeriodicityJEE Coordination CompoundsJEE Inverse Trigonometric FunctionsJEE Kinetic Theory of GasesJEE Carboxylic AcidsJEE Hydrocarbons - AlkanesJEE d and f-Block ElementsJEE StatisticsJEE LimitsJEE Laws of MotionJEE Electronic DevicesJEE Continuity & DifferentiabilityJEE Sets, Relations & FunctionsJEE Work, Energy & PowerJEE Straight LinesJEE Surface TensionJEE Vector AlgebraJEE ElectrochemistryJEE Kinematics - 2D MotionJEE Chemical KineticsJEE Magnetic Effects of CurrentJEE Binomial TheoremJEE Definite IntegrationJEE ProbabilityJEE Sequences & SeriesJEE Hydrocarbons - AromaticJEE Chemical Bonding & Molecular StructureJEE Hydrocarbons - AlkenesJEE Quadratic EquationsJEE DifferentiationJEE GravitationJEE JEE 2D GeometryJEE p-Block Elements (Groups 13-18)JEE Wave OpticsJEE BiomoleculesJEE Heat TransferJEE Current & ResistanceJEE MatricesJEE Differential EquationsJEE EquilibriumJEE WavesJEE Indefinite IntegrationJEE Electric Potential & CapacitanceJEE Conic Sections
Ask AI