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Question 57

A KCl solution of conductivity 0.14 S m$$^{-1}$$ shows a resistance of 4.19$$\Omega$$ in a conductivity cell. If the same cell is filled with an HCl solution, the resistance drops to 1.03$$\Omega$$. The conductivity of the HCl solution is ________ $$\times 10^{-2}$$ S m$$^{-1}$$. (Round off to the Nearest Integer).


Correct Answer: 57

The cell constant $$G^*$$ of a conductivity cell is related to the conductivity $$\kappa$$ and the resistance $$R$$ by the formula $$\kappa = \frac{G^*}{R}$$, or equivalently $$G^* = \kappa \times R$$.

Using the KCl solution data to find the cell constant:

$$G^* = \kappa_{\text{KCl}} \times R_{\text{KCl}} = 0.14 \times 4.19 = 0.5866 \text{ m}^{-1}$$

Now using this cell constant with the HCl solution:

$$\kappa_{\text{HCl}} = \frac{G^*}{R_{\text{HCl}}} = \frac{0.5866}{1.03} = 0.5695 \text{ S m}^{-1}$$

Converting to the required format of $$\times 10^{-2} \text{ S m}^{-1}$$:

$$\kappa_{\text{HCl}} = 56.95 \times 10^{-2} \text{ S m}^{-1}$$

Rounding to the nearest integer, this gives $$57 \times 10^{-2} \text{ S m}^{-1}$$.

The answer is 57.

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