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Question 56

$$2MnO_4^- + bI^- + cH_2O \rightarrow xI_2 + yMnO_2 + zOH^-$$
If the above equation is balanced with integer coefficients, the value of $$z$$ is ________.


Correct Answer: 8

We need to balance the redox equation in basic medium: $$2MnO_4^- + bI^- + cH_2O \rightarrow xI_2 + yMnO_2 + zOH^-$$.

Mn in $$MnO_4^-$$ is +7 and in $$MnO_2$$ is +4, so manganese is reduced by gaining three electrons. Iodine in $$I^-$$ is -1 and in $$I_2$$ is 0, so iodine is oxidized by losing one electron.

In basic medium the half-reactions are written as follows. The reduction half-reaction is $$MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-$$ and the oxidation half-reaction is $$2I^- \rightarrow I_2 + 2e^-$$.

To equalize the electrons exchanged, multiply the reduction half-reaction by 2 and the oxidation half-reaction by 3, giving: $$2MnO_4^- + 4H_2O + 6e^- \rightarrow 2MnO_2 + 8OH^-$$ and $$6I^- \rightarrow 3I_2 + 6e^-$$.

Adding these half-reactions yields the balanced overall equation: $$2MnO_4^- + 6I^- + 4H_2O \rightarrow 3I_2 + 2MnO_2 + 8OH^-$$.

Verification confirms that manganese, iodine, oxygen, hydrogen, and charge are all balanced.

From the balanced equation: $$z = 8$$

Answer: 8

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