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Question 53

The total change in the oxidation state of manganese involved in the reaction of KMnO$$_4$$ and potassium iodide in the acidic medium is _____.


Correct Answer: 5

In acidic medium, KMnO₄ reacts with KI:

$$2KMnO_4 + 10KI + 8H_2SO_4 \to 2MnSO_4 + 5I_2 + 6K_2SO_4 + 8H_2O$$

Manganese changes from +7 (in KMnO₄) to +2 (in MnSO₄).

Total change in oxidation state = 7 - 2 = 5.

This matches the answer key value of $$\mathbf{5}$$.

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