Join WhatsApp Icon JEE WhatsApp Group
Question 52

The element that usually does NOT show variable oxidation states is:

We recall that in the transition series the possibility of showing many oxidation states comes from the participation of both the outer $$ns$$ electrons and the inner $$(n-1)d$$ electrons in bonding. Whenever more electrons of similar energy are available, an atom can lose different numbers of them and thus display variable oxidation states.

However, the very first element of a transition series possesses only one $$d$$ electron (electronic configuration $$[Ar]\;3d^{1}4s^{2}$$ for scandium, $$[Kr]\;4d^{1}5s^{2}$$ for yttrium, etc.). After losing all three of these outer-shell electrons, the ion attains the noble-gas core and becomes exceptionally stable. Because no other $$d$$ or $$s$$ electrons of comparable energy remain, the atom cannot normally lose a different number of electrons. Therefore such first-row elements generally show a single common oxidation state of $$+3$$.

Let us examine each option one by one.

For copper, the ground-state configuration is $$[Ar]\;3d^{10}4s^{1}$$. Removing only the $$4s$$ electron gives $$\mathrm{Cu^{+}}$$ with oxidation state $$+1$$, while removing one more $$3d$$ electron gives $$\mathrm{Cu^{2+}}$$ with oxidation state $$+2$$. So copper definitely shows variable oxidation states.

For titanium, the configuration is $$[Ar]\;3d^{2}4s^{2}$$. It can lose $$2,\;3,$$ or $$4$$ electrons, leading respectively to $$\mathrm{Ti^{2+}},\;Ti^{3+},\;Ti^{4+}$$, so titanium also exhibits several oxidation states.

For scandium, the configuration is $$[Ar]\;3d^{1}4s^{2}$$. Losing all three outer electrons gives $$\mathrm{Sc^{3+}}$$ with oxidation state $$+3$$, and this ion has the stable noble-gas configuration $$[Ar]$$. Because removal of any fewer or any additional electrons is highly unfavorable, scandium is found almost exclusively in the $$+3$$ state and thus does not show variable oxidation states.

For vanadium, the configuration is $$[Ar]\;3d^{3}4s^{2}$$. It can form $$\mathrm{V^{2+}},\;V^{3+},\;V^{4+},\;V^{5+}$$, corresponding to oxidation states $$+2,\;+3,\;+4,\;+5$$, clearly demonstrating variability.

Among the four given elements, only scandium lacks such variability.

Hence, the correct answer is Option C.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI