Join WhatsApp Icon JEE WhatsApp Group
Question 33

Match List I with List II

List I (molecules/ions)List II (No. of lone pairs of e$$^-$$ on central atom)
(A) IF$$_7$$I. Three
(B) ICl$$_4^-$$II. One
(C) XeF$$_6$$III. Two
(D) XeF$$_2$$IV. Zero


Choose the correct answer from the options given below:

We need to match each molecule/ion with the number of lone pairs on its central atom.

(A) IF$$_7$$:

Iodine has 7 valence electrons. It forms 7 bonds with 7 fluorine atoms, using all its valence electrons for bonding. The hybridization is $$sp^3d^3$$.

Lone pairs on I = $$\frac{7 - 7}{2} = 0$$ (Zero) --> matches IV

(B) ICl$$_4^-$$:

Iodine has 7 valence electrons, plus 1 from the negative charge = 8 electrons available. It forms 4 bonds with Cl atoms, leaving 4 non-bonding electrons.

Lone pairs on I = $$\frac{8 - 4}{2} = 2$$ (Two) --> matches III

The geometry is square planar ($$sp^3d^2$$, with 2 lone pairs in axial positions of the octahedron).

(C) XeF$$_6$$:

Xenon has 8 valence electrons. It forms 6 bonds with F atoms, leaving 2 non-bonding electrons.

Lone pairs on Xe = $$\frac{8 - 6}{2} = 1$$ (One) --> matches II

The geometry is distorted octahedral ($$sp^3d^3$$ hybridization with 1 lone pair).

(D) XeF$$_2$$:

Xenon has 8 valence electrons. It forms 2 bonds with F atoms, leaving 6 non-bonding electrons.

Lone pairs on Xe = $$\frac{8 - 2}{2} = 3$$ (Three) --> matches I

The geometry is linear ($$sp^3d$$ hybridization with 3 lone pairs in equatorial positions of a trigonal bipyramid).

The correct matching is: A-IV, B-III, C-II, D-I.

The correct answer is Option 2.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Atomic StructureJEE Applications of DerivativesJEE Complex NumbersJEE Fluid MechanicsJEE Alcohols, Phenols & EthersJEE Basic Principles of Organic ChemistryJEE Trigonometric FunctionsJEE Three Dimensional GeometryJEE Electromagnetic WavesJEE Redox ReactionsJEE SolutionsJEE Laws of ThermodynamicsJEE Ray OpticsJEE Organic Compounds with HalogensJEE Chemical ThermodynamicsJEE Permutations & CombinationsJEE DeterminantsJEE EMF & Circuit AnalysisJEE Aldehydes & KetonesJEE Atoms & NucleiJEE Dual Nature of Matter & RadiationJEE Electric Charges & FieldsJEE Number SystemJEE Units & MeasurementsJEE Simple Harmonic MotionJEE ElasticityJEE Alternating CurrentsJEE Practical Organic ChemistryJEE Electromagnetic InductionJEE Rotational MotionJEE Hydrocarbons - AlkynesJEE CirclesJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Nitrogen-Containing CompoundsJEE Magnetism & Magnetic MaterialsJEE Basic Concepts in ChemistryJEE Laboratory Experiments - XIJEE Periodic Table & PeriodicityJEE Coordination CompoundsJEE Inverse Trigonometric FunctionsJEE Kinetic Theory of GasesJEE Carboxylic AcidsJEE Hydrocarbons - AlkanesJEE d and f-Block ElementsJEE StatisticsJEE LimitsJEE Laws of MotionJEE Electronic DevicesJEE Continuity & DifferentiabilityJEE Sets, Relations & FunctionsJEE Work, Energy & PowerJEE Straight LinesJEE Surface TensionJEE Vector AlgebraJEE ElectrochemistryJEE Kinematics - 2D MotionJEE Chemical KineticsJEE Magnetic Effects of CurrentJEE Binomial TheoremJEE Definite IntegrationJEE ProbabilityJEE Sequences & SeriesJEE Hydrocarbons - AromaticJEE Chemical Bonding & Molecular StructureJEE Hydrocarbons - AlkenesJEE Quadratic EquationsJEE DifferentiationJEE GravitationJEE JEE 2D GeometryJEE p-Block Elements (Groups 13-18)JEE Wave OpticsJEE BiomoleculesJEE Heat TransferJEE Current & ResistanceJEE MatricesJEE Differential EquationsJEE EquilibriumJEE WavesJEE Indefinite IntegrationJEE Electric Potential & CapacitanceJEE Conic Sections
Ask AI