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Question 69

The incorrect statement from the following with respect to carbohydrates is :

  • Statement A is correct: All monosaccharides (whether aldoses or ketoses) are reducing sugars because they possess a free or potentially free aldehyde or ketone group that can reduce Tollen's or Fehling's reagents.
  • Statement B is incorrect: Oligosaccharides can yield different types of monosaccharides upon hydrolysis. For example, Sucrose (a disaccharide) hydrolyzes to give one molecule of glucose and one molecule of fructose, which are different units.
  • Statement C is correct: Polysaccharides like starch and cellulose are high molecular weight polymers consisting of hundreds to thousands of monosaccharide units.
  • Statement D is correct: In aqueous solution, sugars like D-glucose exist in an equilibrium between their open-chain form and their cyclic $$\alpha\ and\ \beta\ $$ anomers.
  • Therefore, Option B is Correct 

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