Join WhatsApp Icon JEE WhatsApp Group
Question 64

Given below are two statements:
Statement I: $$CrO_3$$ is a stronger oxidizing agent than $$MoO_3$$.
Statement II: Cr(VI) is more stable than Mo(VI).
In the light of above statements, Choose the correct answer from the options given below :

The elements chromium (Cr) and molybdenum (Mo) belong to Group 6 of the periodic table. They show their highest oxidation state of $$+6$$ in compounds such as $$CrO_3$$ and $$MoO_3$$.

Case 1: Relative oxidising power of $$CrO_3$$ and $$MoO_3$$
Within a group, the stability of the highest oxidation state generally increases down the group because the heavier element’s larger size and greater ability to delocalise charge stabilise the high oxidation state.
Hence, $$Mo(VI)$$ is more stable than $$Cr(VI)$$.
Less-stable high oxidation states have a stronger tendency to gain electrons (that is, to get reduced to a lower oxidation state). Therefore they behave as stronger oxidising agents.

Since $$Cr(VI)$$ is less stable, $$CrO_3$$ wants to get reduced more readily than $$MoO_3$$. Thus $$CrO_3$$ is the stronger oxidising agent.

Case 2: Comparative stability of $$Cr(VI)$$ and $$Mo(VI)$$
As argued above, the stability of the $$+6$$ state increases from Cr to Mo. Consequently, $$Mo(VI)$$ is more stable while $$Cr(VI)$$ is less stable.

Evaluation of the statements
• Statement I: “$$CrO_3$$ is a stronger oxidising agent than $$MoO_3$$.” - True.
• Statement II: “Cr(VI) is more stable than Mo(VI).” - False (the reverse is correct).

Therefore, Statement I is true but Statement II is false. The correct choice is Option B.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

50,000+ JEE Students Trusted Our Score Calculator

Predict your JEE Main percentile, rank & performance in seconds

Ask AI

Ask our AI anything

AI can make mistakes. Please verify important information.