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Neoprene is a synthetic rubber formed by the free radical polymerization of its monomer, Chloroprene.
Monomer: 2-chloro-1,3-butadiene ($$CH_2=C(Cl)-CH=CH_2$$).
$$n[CH_2=C(Cl)-CH=CH_2] \xrightarrow{\text{Polymerization}} \text{---}(CH_2-C(Cl)=CH-CH_2)\text{---}_n$$
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