Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
The reaction rate for the reaction
$$[PtCl_4]^{2-} + H_2O \rightleftharpoons [Pt(H_2O)Cl_3]^- + Cl^-$$
was measured as a function of concentrations of different species. It was observed that
$$\frac{-d[PtCl_4]^{2-}}{dt} = 4.8 \times 10^{-5}[PtCl_4]^{2-} - 2.4 \times 10^{-3}[Pt(H_2O)Cl_3]^-][Cl^-]$$
where square brackets are used to denote molar concentrations.
The equilibrium constant K$$_c$$ = X (Nearest integer). Value of $$\frac{1}{X}$$ is _________
$$K_c = X$$ (Nearest integer)
Correct Answer: 50
We start with the elementary reversible reaction
$$[PtCl_4]^{2-} + H_2O \;\rightleftharpoons\; [Pt(H_2O)Cl_3]^- + Cl^-$$
The experimentally observed rate law for the disappearance of $$[PtCl_4]^{2-}$$ is
$$-\dfrac{d[PtCl_4]^{2-}}{dt}=4.8\times10^{-5}[PtCl_4]^{2-}-2.4\times10^{-3}[Pt(H_2O)Cl_3]^-\, [Cl^-]$$
We recognise the right-hand side as the difference between a forward rate and a backward rate, so we write
$$\text{rate}_{\text{net}}=\text{rate}_{\text{forward}}-\text{rate}_{\text{backward}}$$
and compare term by term:
$$\text{rate}_{\text{forward}}=k_f[PtCl_4]^{2-}$$ $$\text{rate}_{\text{backward}}=k_b[Pt(H_2O)Cl_3]^-\, [Cl^-]$$
Matching coefficients gives
$$k_f = 4.8\times10^{-5}\;\text{s}^{-1}$$ $$k_b = 2.4\times10^{-3}\;\text{M}^{-1}\text{s}^{-1}$$
At equilibrium the net rate is zero, so the forward and backward rates are equal:
$$k_f[PtCl_4]^{2-}=k_b[Pt(H_2O)Cl_3]^-\, [Cl^-]$$
Rearranging we obtain
$$\dfrac{[Pt(H_2O)Cl_3]^-\, [Cl^-]}{[PtCl_4]^{2-}}=\dfrac{k_f}{k_b}$$
By definition the equilibrium constant for the reaction is
$$K_c=\dfrac{[Pt(H_2O)Cl_3]^-\, [Cl^-]}{[PtCl_4]^{2-}}$$
Therefore
$$K_c=\dfrac{k_f}{k_b}$$
Substituting the numerical values, we have
$$K_c=\dfrac{4.8\times10^{-5}}{2.4\times10^{-3}}$$
Now we divide the mantissas first:
$$\dfrac{4.8}{2.4}=2$$
Next we divide the powers of ten:
$$10^{-5}\div10^{-3}=10^{(-5)-(-3)}=10^{-2}$$
Multiplying these two results together we find
$$K_c = 2\times10^{-2}=0.02$$
The problem asks us to denote this value by $$X$$ and then evaluate $$\dfrac{1}{X}$$. Hence
$$X=0.02\quad\Longrightarrow\quad\dfrac{1}{X}=\dfrac{1}{0.02}=50$$
So, the answer is $$50$$.
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.