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Question 54

$$A(g) \rightleftharpoons 2B(g) + C(g)$$
For the given reaction, if the initial pressure is 450 mmHg and the pressure at time t is 720 mmHg at a constant temperature T and constant volume V. The fraction of A(g) decomposed under these conditions is $$x \times 10^{-1}$$. The value of x is (nearest integer) _______


Correct Answer: 3

We are given the reaction $$A(g) \rightleftharpoons 2B(g) + C(g)$$ with initial pressure 450 mmHg and total pressure at time $$t$$ equal to 720 mmHg. We need to find the fraction of A decomposed.

Let $$x$$ be the fraction of A that has decomposed. Initially, only A is present at 450 mmHg.

A2BC
Initial (mmHg)45000
Change$$-450x$$$$+900x$$$$+450x$$
At time t$$450(1-x)$$$$900x$$$$450x$$

The stoichiometry tells us: for every mole of A that decomposes, 2 moles of B and 1 mole of C are formed.

$$P_{total} = 450(1-x) + 900x + 450x$$ $$720 = 450 - 450x + 900x + 450x$$ $$720 = 450 + 900x$$ $$900x = 720 - 450 = 270$$ $$x = \frac{270}{900} = 0.3 = \frac{3}{10}$$

The fraction of A decomposed is $$\frac{3}{10}$$. Expressed as a ratio, the numerator is 3.

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