Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
$$A(g) \rightleftharpoons 2B(g) + C(g)$$
For the given reaction, if the initial pressure is 450 mmHg and the pressure at time t is 720 mmHg at a constant temperature T and constant volume V. The fraction of A(g) decomposed under these conditions is $$x \times 10^{-1}$$. The value of x is (nearest integer) _______
Correct Answer: 3
We are given the reaction $$A(g) \rightleftharpoons 2B(g) + C(g)$$ with initial pressure 450 mmHg and total pressure at time $$t$$ equal to 720 mmHg. We need to find the fraction of A decomposed.
Let $$x$$ be the fraction of A that has decomposed. Initially, only A is present at 450 mmHg.
| A | 2B | C | |
|---|---|---|---|
| Initial (mmHg) | 450 | 0 | 0 |
| Change | $$-450x$$ | $$+900x$$ | $$+450x$$ |
| At time t | $$450(1-x)$$ | $$900x$$ | $$450x$$ |
The stoichiometry tells us: for every mole of A that decomposes, 2 moles of B and 1 mole of C are formed.
$$P_{total} = 450(1-x) + 900x + 450x$$ $$720 = 450 - 450x + 900x + 450x$$ $$720 = 450 + 900x$$ $$900x = 720 - 450 = 270$$ $$x = \frac{270}{900} = 0.3 = \frac{3}{10}$$The fraction of A decomposed is $$\frac{3}{10}$$. Expressed as a ratio, the numerator is 3.
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.