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Question 53

At 25°C, 50 g of iron reacts with HCl to form $$FeCl_2$$. The evolved hydrogen gas expands against a constant pressure of 1 bar. The work done by the gas during this expansion is ________ J. (Round off to the Nearest Integer)
[Given: $$R = 8.314$$ J mol$$^{-1}$$ K$$^{-1}$$. Assume, hydrogen is an ideal gas]
[Atomic mass of Fe is 55.85 u]


Correct Answer: 2218

The reaction of iron with hydrochloric acid is: $$Fe + 2HCl \rightarrow FeCl_2 + H_2 \uparrow$$.

Moles of iron = $$\frac{50}{55.85} = 0.8953$$ mol. Since each mole of iron produces one mole of hydrogen gas, moles of $$H_2$$ produced = $$0.8953$$ mol.

The work done by the gas expanding against a constant external pressure of 1 bar is given by $$W = nRT$$ (for an ideal gas expanding at constant pressure where $$\Delta n_{gas} = n$$, since the reactants are in condensed/solution phase).

At 25°C (298 K): $$W = nRT = 0.8953 \times 8.314 \times 298 = 2218.1$$ J.

Alternatively, using $$W = P\Delta V = P \cdot nRT/P = nRT$$, we get the same result since the initial volume of gas is zero and the final volume is $$V = nRT/P$$.

The work done by the gas during this expansion is $$2218$$ J.

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