Join WhatsApp Icon JEE WhatsApp Group
Question 52

AB$$_3$$ is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is _________ (Integer answer)


Correct Answer: 2

We are told that the molecule is an inter-halogen of the type $$\mathrm{AB_3}$$ and that its observed geometry is T-shaped. In any VSEPR (Valence Shell Electron Pair Repulsion) discussion we first count total electron pairs around the central atom $$\mathrm A$$, because the geometry is fixed by the steric number (total regions of electron density = bond pairs + lone pairs).

Each halogen atom has seven valence electrons. Therefore the central halogen $$\mathrm A$$ also possesses $$7$$ valence electrons. We now account for the three $$\mathrm{A{-}B}$$ single bonds.

Every single (sigma) bond is a bond pair involving one electron from $$\mathrm A$$ and one from $$\mathrm B$$. So the three $$\mathrm{A{-}B}$$ bonds consume $$3$$ of the $$7$$ valence electrons of $$\mathrm A$$:

$$7\;(\text{valence electrons of A}) \;-\;3\;(\text{electrons used in three } \sigma\text{ bonds}) \;=\;4$$

The $$4$$ electrons that remain on $$\mathrm A$$ must stay as non-bonding electrons. Because two electrons make one lone pair, we have

$$\dfrac{4\; \text{non-bonding electrons}}{2\; \text{electrons per lone pair}} \;=\;2\; \text{lone pairs}.$$

Hence the electron-pair distribution around $$\mathrm A$$ is

$$3 \text{ bond pairs } + 2 \text{ lone pairs } = 5 \text{ regions of electron density}.$$

According to VSEPR theory, five regions adopt a trigonal-bipyramidal arrangement. When two of those five positions are occupied by lone pairs (preferentially the equatorial sites, because 90° repulsions are minimized), the three bond pairs occupy the remaining positions and the molecular shape observed is T-shaped, exactly as stated in the question. This matches the description $$\mathrm{AB_3E_2}$$, where $$\mathrm E$$ denotes a lone pair.

So, the number of lone pairs on the central atom $$\mathrm A$$ is clearly

$$2.$$

Hence, the correct answer is Option C.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI