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Question 47

In some solutions, the concentration of H$$_3$$O$$^+$$ remains constant even when small amounts of strong acid or strong base are added to them. These solutions are known as:

The question describes a special property of certain solutions: the concentration of hydronium ions, $$H_3O^+$$, stays almost the same even when small quantities of strong acid or strong base are added to them. This stability in $$H_3O^+$$ concentration means the pH of the solution does not change significantly, which is a key characteristic for many chemical and biological processes where constant pH is essential.

Solutions that exhibit this behavior are known as buffer solutions. A buffer solution typically consists of a weak acid mixed with its conjugate base or a weak base mixed with its conjugate acid. For example, a common buffer is made from acetic acid $$(CH_3COOH)$$ and sodium acetate $$(CH_3COONa)$$, where acetate ion $$(CH_3COO^-)$$ is the conjugate base. When a small amount of strong acid, like hydrochloric acid $$(HCl)$$, is added, the conjugate base (acetate ion) reacts with the added $$H^+$$ to form more weak acid (acetic acid). The reaction can be written as: $$CH_3COO^- + H^+ \rightarrow CH_3COOH$$. Since acetic acid is weak and does not dissociate much, the increase in $$H_3O^+$$ concentration is minimal. Similarly, when a small amount of strong base, like sodium hydroxide $$(NaOH)$$, is added, the weak acid (acetic acid) reacts with the added $$OH^-$$ to form water and the conjugate base: $$CH_3COOH + OH^- \rightarrow CH_3COO^- + H_2O$$. This reaction consumes the $$OH^-$$, preventing a large decrease in $$H_3O^+$$ concentration. The ability to resist pH changes is mathematically described by the Henderson-Hasselbalch equation: $$\text{pH} = \text{p}K_a + \log\left(\frac{[\text{conjugate base}]}{[\text{weak acid}]}\right)$$. As long as the ratio of conjugate base to weak acid remains nearly constant, which it does for small additions of acid or base, the pH stays stable.

Now, let's examine why the other options do not fit this description. Option A, ideal solutions, refers to mixtures that obey Raoult's law throughout all concentrations, such as benzene and toluene. These solutions do not necessarily contain components that buffer pH; adding strong acid or base would alter the $$H_3O^+$$ concentration significantly. Option B, colloidal solutions, are heterogeneous mixtures where particles are larger than in true solutions, like milk or fog. They lack the specific acid-base pairs needed for buffering, and adding acid or base can cause precipitation or other changes without maintaining constant $$H_3O^+$$. Option C, true solutions, are homogeneous mixtures with dissolved particles at the molecular or ionic level, such as salt water. While buffer solutions are a type of true solution, not all true solutions are buffers. For instance, a solution of sodium chloride $$(NaCl)$$ in water has no buffering capacity; adding even a small amount of acid or base changes the $$H_3O^+$$ concentration drastically.

Therefore, only buffer solutions have the unique ability to keep the $$H_3O^+$$ concentration constant upon addition of small amounts of strong acid or base. Hence, the correct answer is Option D.

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