Join WhatsApp Icon JEE WhatsApp Group
Question 44

For an ideal solution of two components A & B, which of the following is true?

For an ideal solution of two components A and B, we need to determine which statement is true among the given options. Let's recall the definition of an ideal solution.

An ideal solution is one where the intermolecular forces between the different components are identical to the intermolecular forces within the same components. This means that the A-B interactions (between molecules of A and B) are equal in strength to the A-A interactions (between molecules of A) and the B-B interactions (between molecules of B).

Now, consider the enthalpy change during mixing, denoted as $$\Delta H_{\text{mixing}}$$. Enthalpy change is related to the energy changes in breaking and forming intermolecular bonds. In an ideal solution, since the A-B interactions are the same as A-A and B-B interactions, there is no net energy change when the components mix. Breaking some A-A and B-B bonds requires energy, but forming A-B bonds releases the same amount of energy. Therefore, the net enthalpy change is zero:

$$\Delta H_{\text{mixing}} = 0$$

Now, let's evaluate each option:

Option A states: $$\Delta H_{\text{mixing}} > 0$$ (zero). This means the enthalpy of mixing is greater than zero, implying an endothermic process. However, for an ideal solution, $$\Delta H_{\text{mixing}} = 0$$, not greater than zero. So, this option is incorrect.

Option B states: A-B interaction is stronger than A-A and B-B interactions. If A-B interactions were stronger, then forming A-B bonds would release more energy than breaking A-A and B-B bonds requires. This would make $$\Delta H_{\text{mixing}} < 0$$ (negative). But in an ideal solution, $$\Delta H_{\text{mixing}} = 0$$, so the interactions must be equal, not stronger. Thus, this option is false.

Option C states: A-A, B-B, and A-B interactions are identical. This means the strength of the interactions between A-A, B-B, and A-B are the same. This aligns perfectly with the definition of an ideal solution, where the intermolecular forces are uniform. Therefore, this option is correct.

Option D states: $$\Delta H_{\text{mixing}} < 0$$ (zero). This means the enthalpy of mixing is less than zero, implying an exothermic process. However, for an ideal solution, $$\Delta H_{\text{mixing}} = 0$$, not less than zero. So, this option is incorrect.

Hence, the correct answer is Option C.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Atomic StructureJEE Applications of DerivativesJEE Complex NumbersJEE Fluid MechanicsJEE Alcohols, Phenols & EthersJEE Basic Principles of Organic ChemistryJEE Trigonometric FunctionsJEE Three Dimensional GeometryJEE Electromagnetic WavesJEE Redox ReactionsJEE SolutionsJEE Laws of ThermodynamicsJEE Ray OpticsJEE Organic Compounds with HalogensJEE Chemical ThermodynamicsJEE Permutations & CombinationsJEE DeterminantsJEE EMF & Circuit AnalysisJEE Aldehydes & KetonesJEE Atoms & NucleiJEE Dual Nature of Matter & RadiationJEE Electric Charges & FieldsJEE Number SystemJEE Units & MeasurementsJEE Simple Harmonic MotionJEE ElasticityJEE Alternating CurrentsJEE Practical Organic ChemistryJEE Electromagnetic InductionJEE Rotational MotionJEE Hydrocarbons - AlkynesJEE CirclesJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Nitrogen-Containing CompoundsJEE Magnetism & Magnetic MaterialsJEE Basic Concepts in ChemistryJEE Laboratory Experiments - XIJEE Periodic Table & PeriodicityJEE Coordination CompoundsJEE Inverse Trigonometric FunctionsJEE Kinetic Theory of GasesJEE Carboxylic AcidsJEE Hydrocarbons - AlkanesJEE d and f-Block ElementsJEE StatisticsJEE LimitsJEE Laws of MotionJEE Electronic DevicesJEE Continuity & DifferentiabilityJEE Sets, Relations & FunctionsJEE Work, Energy & PowerJEE Straight LinesJEE Surface TensionJEE Vector AlgebraJEE ElectrochemistryJEE Kinematics - 2D MotionJEE Chemical KineticsJEE Magnetic Effects of CurrentJEE Binomial TheoremJEE Definite IntegrationJEE ProbabilityJEE Sequences & SeriesJEE Hydrocarbons - AromaticJEE Chemical Bonding & Molecular StructureJEE Hydrocarbons - AlkenesJEE Quadratic EquationsJEE DifferentiationJEE GravitationJEE JEE 2D GeometryJEE p-Block Elements (Groups 13-18)JEE Wave OpticsJEE BiomoleculesJEE Heat TransferJEE Current & ResistanceJEE MatricesJEE Differential EquationsJEE EquilibriumJEE WavesJEE Indefinite IntegrationJEE Electric Potential & CapacitanceJEE Conic Sections
Ask AI