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A solution of two miscible liquids showing negative deviation from Raoult's law will have :
A solution showing negative deviation from Raoult's law has stronger intermolecular forces between unlike molecules than like molecules.
This results in:
- Decreased vapour pressure (molecules are held more tightly in solution, fewer escape to vapor phase)
- Increased boiling point (higher temperature needed to reach atmospheric pressure since vapour pressure is lower)
The answer is: decreased vapour pressure, increased boiling point, which corresponds to Option (4).
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