Join WhatsApp Icon JEE WhatsApp Group
Question 38

The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is:

Understanding resonance energy:

Many organic compounds can be represented by two or more Lewis structures (called resonance structures or canonical structures). The actual molecule is a resonance hybrid of all these structures.

The lowest energy resonance structure (also called the most stable contributing structure) is a hypothetical reference. The actual molecule, being a hybrid of all resonance structures, has a lower energy than any single resonance structure — including the most stable one.

Definition of resonance energy:

Resonance energy is defined as the difference in energy between the actual structure (resonance hybrid) and the most stable (lowest energy) resonance structure:

$$\text{Resonance Energy} = E_{\text{lowest energy resonance structure}} - E_{\text{actual structure (hybrid)}}$$

Since the actual structure is always more stable (lower energy) than any individual resonance structure, the resonance energy is always a positive quantity.

For example, benzene has a resonance energy of approximately 150 kJ/mol, meaning the actual benzene molecule is 150 kJ/mol more stable than the hypothetical cyclohexatriene (Kekulé) structure.

Among the given options:

Option A (electromeric energy): This refers to the temporary shift of electrons in a multiple bond under the influence of an attacking reagent. It is not related to the stability difference between resonance structures.

Option B (resonance energy): This is exactly the energy difference between the actual structure and the lowest energy resonance structure. This is correct.

Option C (ionization energy): This is the energy required to remove an electron from an isolated gaseous atom. Unrelated to resonance.

Option D (hyperconjugation energy): This refers to the stabilization due to the interaction of electrons in a $$\sigma$$ bond with an adjacent empty or partially filled p-orbital. While it contributes to stability, it is not defined as the difference between the actual and resonance structures.

The correct answer is Option B: resonance energy.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI