Sign in
Please select an account to continue using cracku.in
↓ →
The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is:
Understanding resonance energy:
Many organic compounds can be represented by two or more Lewis structures (called resonance structures or canonical structures). The actual molecule is a resonance hybrid of all these structures.
The lowest energy resonance structure (also called the most stable contributing structure) is a hypothetical reference. The actual molecule, being a hybrid of all resonance structures, has a lower energy than any single resonance structure — including the most stable one.
Definition of resonance energy:
Resonance energy is defined as the difference in energy between the actual structure (resonance hybrid) and the most stable (lowest energy) resonance structure:
$$\text{Resonance Energy} = E_{\text{lowest energy resonance structure}} - E_{\text{actual structure (hybrid)}}$$
Since the actual structure is always more stable (lower energy) than any individual resonance structure, the resonance energy is always a positive quantity.
For example, benzene has a resonance energy of approximately 150 kJ/mol, meaning the actual benzene molecule is 150 kJ/mol more stable than the hypothetical cyclohexatriene (Kekulé) structure.
Among the given options:
Option A (electromeric energy): This refers to the temporary shift of electrons in a multiple bond under the influence of an attacking reagent. It is not related to the stability difference between resonance structures.
Option B (resonance energy): This is exactly the energy difference between the actual structure and the lowest energy resonance structure. This is correct.
Option C (ionization energy): This is the energy required to remove an electron from an isolated gaseous atom. Unrelated to resonance.
Option D (hyperconjugation energy): This refers to the stabilization due to the interaction of electrons in a $$\sigma$$ bond with an adjacent empty or partially filled p-orbital. While it contributes to stability, it is not defined as the difference between the actual and resonance structures.
The correct answer is Option B: resonance energy.
Create a FREE account and get:
Educational materials for JEE preparation