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Match List I with List II.
| List I | List II |
|---|---|
| A. van't Hoff factor, i | I. Cryoscopic constant |
| B. k$$_f$$ | II. Isotonic solutions |
| C. Solutions with same osmotic pressure | III. $$\frac{\text{Normal molar mass}}{\text{Abnormal molar mass}}$$ |
| D. Azeotropes | IV. Solutions with same composition of vapour above it |
We need to match List I with List II for concepts related to solutions.
A. van't Hoff factor, $$i$$:
The van't Hoff factor is defined as:
$$i = \frac{\text{Normal molar mass}}{\text{Abnormal molar mass}}$$
This matches with III.
B. $$K_f$$:
$$K_f$$ is the cryoscopic constant (molal depression constant for freezing point).
This matches with I.
C. Solutions with same osmotic pressure:
Solutions having the same osmotic pressure are called isotonic solutions.
This matches with II.
D. Azeotropes:
Azeotropes are solutions that have the same composition in the liquid and vapour phase. They boil at a constant temperature and the vapour has the same composition as the liquid.
This matches with IV (solutions with same composition of vapour above it).
The correct answer is Option A: A-III, B-I, C-II, D-IV.
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