Join WhatsApp Icon JEE WhatsApp Group
Question 38

Given below are two statements.
Statement I: The presence of weaker $$\pi$$-bonds make alkenes less stable than alkanes
Statement II: The strength of the double bond is greater than that of carbon-carbon single bond.
In the light of the above statements, choose the correct answer from the options given below.

We need to evaluate both statements about alkenes and alkanes.

Statement I: "The presence of weaker $$\pi$$-bonds make alkenes less stable than alkanes."

The $$\pi$$ bond in alkenes is formed by the lateral overlap of unhybridized p-orbitals. This lateral overlap is less effective than the head-on overlap in $$\sigma$$ bonds, making the $$\pi$$ bond weaker and more reactive. Due to the presence of this weaker $$\pi$$ bond, alkenes are more reactive (less stable) than alkanes, which contain only strong $$\sigma$$ bonds.

Statement I is correct.

Statement II: "The strength of the double bond is greater than that of carbon-carbon single bond."

The bond energy of a C=C double bond is approximately $$614$$ kJ/mol, while the bond energy of a C-C single bond is approximately $$347$$ kJ/mol. Since $$614 > 347$$, the double bond is indeed stronger than the single bond overall (even though the $$\pi$$ component individually is weaker than a $$\sigma$$ bond).

Statement II is correct.

Note: There is no contradiction between the two statements. The double bond as a whole is stronger than a single bond, but the presence of the weaker $$\pi$$ bond component makes the molecule more reactive at that site.

The correct answer is Option A: Both Statement I and Statement II are correct.

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI