Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
Given below are two statements.
Statement I: The presence of weaker $$\pi$$-bonds make alkenes less stable than alkanes
Statement II: The strength of the double bond is greater than that of carbon-carbon single bond.
In the light of the above statements, choose the correct answer from the options given below.
We need to evaluate both statements about alkenes and alkanes.
Statement I: "The presence of weaker $$\pi$$-bonds make alkenes less stable than alkanes."
The $$\pi$$ bond in alkenes is formed by the lateral overlap of unhybridized p-orbitals. This lateral overlap is less effective than the head-on overlap in $$\sigma$$ bonds, making the $$\pi$$ bond weaker and more reactive. Due to the presence of this weaker $$\pi$$ bond, alkenes are more reactive (less stable) than alkanes, which contain only strong $$\sigma$$ bonds.
Statement I is correct.
Statement II: "The strength of the double bond is greater than that of carbon-carbon single bond."
The bond energy of a C=C double bond is approximately $$614$$ kJ/mol, while the bond energy of a C-C single bond is approximately $$347$$ kJ/mol. Since $$614 > 347$$, the double bond is indeed stronger than the single bond overall (even though the $$\pi$$ component individually is weaker than a $$\sigma$$ bond).
Statement II is correct.
Note: There is no contradiction between the two statements. The double bond as a whole is stronger than a single bond, but the presence of the weaker $$\pi$$ bond component makes the molecule more reactive at that site.
The correct answer is Option A: Both Statement I and Statement II are correct.
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.