Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
At $$25°$$C and 1 atm pressure, the enthalpies of combustion are as given below:
| Substance | $$H_2$$ | C (graphite) | $$C_2H_6(g)$$ |
|---|---|---|---|
| $$\frac{\Delta_c H^\ominus}{kJ mol^{-1}}$$ | $$-286.0$$ | $$-394.0$$ | $$-1560.0$$ |
The enthalpy of formation of ethane is
We need to find the enthalpy of formation of ethane: $$2C(\text{graphite}) + 3H_2(g) \to C_2H_6(g)$$
Using Hess's Law, the enthalpy of formation can be calculated from combustion data:
$$\Delta_f H^\circ = \sum \Delta_c H^\circ (\text{reactants}) - \Delta_c H^\circ (\text{product})$$
$$\Delta_f H^\circ (C_2H_6) = 2 \times \Delta_c H^\circ (C) + 3 \times \Delta_c H^\circ (H_2) - \Delta_c H^\circ (C_2H_6)$$
Substituting the given values:
$$\Delta_f H^\circ = 2 \times (-394.0) + 3 \times (-286.0) - (-1560.0)$$
$$= -788.0 - 858.0 + 1560.0$$
$$= -1646.0 + 1560.0$$
$$= -86.0 \text{ kJ mol}^{-1}$$
The correct answer is Option C: $$-86.0$$ kJ mol$$^{-1}$$.
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.