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Upon heating $$KClO_{3}$$ in the presence of catalytic amount of $$MnO_{2}$$ a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure $$HNO_{3}$$ gives Y and Z.
Y and Z are, respectively
$$N_{2}O_{3}$$ and $$H_{3}PO_{4}$$
$$N_{2}O_{5}$$ and $$HPO_{3}$$
$$N_{2}O_{4}$$ and $$HPO_{3}$$
$$N_{2}O_{4}$$ and $$H_{3}PO_{3}$$
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