Join WhatsApp Icon JEE WhatsApp Group
Question 32

In general, the properties that decrease and increase down a group in the periodic table, respectively, are:

First, we recall the basic periodic trends that are always examined in questions of this type. Down any family (that is, as we proceed from the top of a vertical column of the periodic table to the bottom) two of the most routinely discussed properties are the atomic (or ionic) radius and the electronegativity.

We start with the atomic radius. As we go from one period to the next period directly below it, one extra principal quantum shell $$n$$ is added. Because the quantum number $$n$$ appears in the Bohr‐type relation $$r \propto n^{2}$$ and also simply counts the number of shells, the size of the electron cloud increases. The inner shells shield the outermost electrons from the full nuclear charge, so the effective nuclear attraction on the valence shell does not grow enough to contract the atom. Hence, the net effect is that the atomic radius increases down a group:

$$\text{Down a group: } r_{\text{atomic}} \uparrow$$

Now we examine electronegativity, the tendency of an atom to attract a shared electron pair toward itself in a covalent bond. A commonly quoted relation for Pauling electronegativity is

$$\chi = \dfrac{A + B}{2} - \sqrt{\Delta},$$

where $$\chi$$ decreases when the atomic size becomes large and the nuclear pull on bonding electrons becomes weaker. Because we have just reasoned that the radius increases down the group, the nucleus is farther away from bonding electrons and, additionally, inner‐shell shielding further reduces the effective nuclear charge. Consequently, the ability to attract bonding electrons decreases down a group:

$$\text{Down a group: } \chi_{\text{electronegativity}} \downarrow$$

Putting these two well-established facts together, we see that one property (electronegativity) decreases while the other (atomic radius) increases as we descend a group.

We now compare this conclusion with the given alternatives:

A. Atomic radius and electronegativity — this would mean radius decreases and electronegativity increases, which contradicts the observed trend.

B. Electronegativity and atomic radius — this states exactly what we derived: electronegativity decreases while atomic radius increases.

C. Electronegativity and electron gain enthalpy — electron gain enthalpy also becomes less negative (i.e., decreases) down a group, not increases, so the second part does not match.

D. Electron gain enthalpy and electronegativity — this implies electron gain enthalpy decreases and electronegativity increases, both of which are opposite to fact.

Therefore, the only option consistent with the proven periodic trends is Option B, which is numbered 2 in the question.

Hence, the correct answer is Option 2.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI