Join WhatsApp Icon JEE WhatsApp Group
Question 28

The first three spectral lines of H-atom in the Balmer series are given $$\lambda_1, \lambda_2, \lambda_3$$ considering the Bohr atomic model, the wave lengths of first and third spectral lines $$\left(\frac{\lambda_1}{\lambda_3}\right)$$ are related by a factor of approximately $$x \times 10^{-1}$$. The value of $$x$$, to the nearest integer, is ________.


Correct Answer: 15

In the Balmer series, the spectral lines correspond to transitions from higher energy levels to $$n = 2$$. The wavelength for a transition from level $$n$$ to level 2 is given by $$\frac{1}{\lambda} = R\left(\frac{1}{2^2} - \frac{1}{n^2}\right)$$, where $$R$$ is the Rydberg constant.

For the first spectral line ($$\lambda_1$$), the transition is from $$n = 3$$ to $$n = 2$$: $$\frac{1}{\lambda_1} = R\left(\frac{1}{4} - \frac{1}{9}\right) = R \cdot \frac{5}{36}$$.

For the third spectral line ($$\lambda_3$$), the transition is from $$n = 5$$ to $$n = 2$$: $$\frac{1}{\lambda_3} = R\left(\frac{1}{4} - \frac{1}{25}\right) = R \cdot \frac{21}{100}$$.

Taking the ratio, $$\frac{\lambda_1}{\lambda_3} = \frac{21/100}{5/36} = \frac{21 \times 36}{100 \times 5} = \frac{756}{500} = 1.512$$.

This can be written as approximately $$15.12 \times 10^{-1}$$, so $$x \approx 15$$ to the nearest integer.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

Free JEE Topicwise Questions

JEE Atomic StructureJEE Applications of DerivativesJEE Complex NumbersJEE Fluid MechanicsJEE Alcohols, Phenols & EthersJEE Basic Principles of Organic ChemistryJEE Trigonometric FunctionsJEE Three Dimensional GeometryJEE Electromagnetic WavesJEE Redox ReactionsJEE SolutionsJEE Laws of ThermodynamicsJEE Ray OpticsJEE Organic Compounds with HalogensJEE Chemical ThermodynamicsJEE Permutations & CombinationsJEE DeterminantsJEE EMF & Circuit AnalysisJEE Aldehydes & KetonesJEE Atoms & NucleiJEE Dual Nature of Matter & RadiationJEE Electric Charges & FieldsJEE Number SystemJEE Units & MeasurementsJEE Simple Harmonic MotionJEE ElasticityJEE Alternating CurrentsJEE Practical Organic ChemistryJEE Electromagnetic InductionJEE Rotational MotionJEE Hydrocarbons - AlkynesJEE CirclesJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Nitrogen-Containing CompoundsJEE Magnetism & Magnetic MaterialsJEE Basic Concepts in ChemistryJEE Laboratory Experiments - XIJEE Periodic Table & PeriodicityJEE Coordination CompoundsJEE Inverse Trigonometric FunctionsJEE Kinetic Theory of GasesJEE Carboxylic AcidsJEE Hydrocarbons - AlkanesJEE d and f-Block ElementsJEE StatisticsJEE LimitsJEE Laws of MotionJEE Electronic DevicesJEE Continuity & DifferentiabilityJEE Sets, Relations & FunctionsJEE Work, Energy & PowerJEE Straight LinesJEE Surface TensionJEE Vector AlgebraJEE ElectrochemistryJEE Kinematics - 2D MotionJEE Chemical KineticsJEE Magnetic Effects of CurrentJEE Binomial TheoremJEE Definite IntegrationJEE ProbabilityJEE Sequences & SeriesJEE Hydrocarbons - AromaticJEE Chemical Bonding & Molecular StructureJEE Hydrocarbons - AlkenesJEE Quadratic EquationsJEE DifferentiationJEE GravitationJEE JEE 2D GeometryJEE p-Block Elements (Groups 13-18)JEE Wave OpticsJEE BiomoleculesJEE Heat TransferJEE Current & ResistanceJEE MatricesJEE Differential EquationsJEE EquilibriumJEE WavesJEE Indefinite IntegrationJEE Electric Potential & CapacitanceJEE Conic Sections
Ask AI