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Question 20

In Bohr's atomic model of hydrogen, let $$K$$, $$P$$ and $$E$$ are the kinetic energy, potential energy and total energy of the electron respectively. Choose the correct option when the electron undergoes transitions to a higher level :

We begin by recalling the energy expressions in Bohr’s model for the $$n$$-th orbit. The kinetic energy is given by:

$$K_n = \frac{13.6}{n^2} \text{ eV}$$

while the potential energy is

$$P_n = -\frac{27.2}{n^2} \text{ eV}$$

and the total energy is

$$E_n = -\frac{13.6}{n^2} \text{ eV}$$

Note that $$K_n$$ is always positive, $$P_n$$ is always negative, and $$E_n = K_n + P_n$$ remains negative.

Since the electron transitions to a higher energy level, $$n$$ increases and consequently $$n^2$$ increases. Substituting this into the kinetic energy expression,

$$K_n = \frac{13.6}{n^2}$$

we see that as $$n$$ increases, the denominator grows and the positive value of $$K_n$$ decreases.

Similarly, for the potential energy

$$P_n = -\frac{27.2}{n^2}$$

the magnitude $$\frac{27.2}{n^2}$$ becomes smaller, so $$P_n$$ becomes less negative and therefore increases (moves closer to zero).

For the total energy

$$E_n = -\frac{13.6}{n^2}$$

the same reduction in magnitude makes $$E_n$$ less negative, meaning that $$E_n$$ also increases (moves closer to zero).

From the above, when the electron moves to a higher level, the kinetic energy decreases, the potential energy increases, and the total energy increases. Therefore, the correct option is Option B.

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