NTA JEE Main 25th July 2021 Shift 2 - Chemistry

Instructions

For the following questions answer them individually

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 31


The spin only magnetic moments (in BM) for free Ti$$^{3+}$$, V$$^{2+}$$ and Sc$$^{3+}$$ ions respectively are (At.No. Sc : 21, Ti : 22, V : 23)

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 32


The ionic radii of F$$^-$$ and O$$^{2-}$$ respectively are 1.33 A and 1.4A, while the covalent radius of N is 0.74A. The correct statement for the ionic radius of N$$^{3-}$$ from the following is:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 33


In the following the correct bond order sequence is:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 34


Identify the species having one $$\pi$$-bond and maximum number of canonical forms from the following:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 35


Identify the process in which change in the oxidation state is five:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 36


Which one of the following metals forms interstitial hydride easily?

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 37


Match List I with List II:
List-I (Elements)   List-II (Properties)
(a) Li   (i) Poor water solubility of I$$^-$$ salt
(b) Na   (ii) Most abundant element in cell fluid
(c) K   (iii) Bicarbonate salt used in fire extinguisher
(d) Cs   (iv) Carbonate salt decomposes easily on heating
Choose the correct answer from the options given below:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 38


The correct decreasing order of densities of the following compounds is:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 39


Which among the following is the strongest acid?

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 40


Given below are two statements:
Statement I : Chlorofluoro carbons breakdown by radiation in the visible energy region and release chlorine gas in the atmosphere which then reacts with stratospheric ozone.
Statement II : Atmospheric ozone reacts with nitric oxide to give nitrogen and oxygen gases, which add to the atmosphere.
For the above statements choose the correct answer from the options given below:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 41


Match List I with List II:
List-I (Example of colloids)          List-II (Classification)
(a) Cheese                                 (i) dispersion of liquid in liquid
(b) Pumice stone                      (ii) dispersion of liquid in gas
(c) Hair cream                           (iii) dispersion of gas in solid
(d) Cloud                                    (iv) dispersion of liquid in solid
Choose the most appropriate answer from the options given below:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 42


Match List I with List II: (Both having metallurgical terms)
List-I                                      List-II
(a) Concentration of Ag ore    (i) Reverberatory furnace
(b) Blast furnace                   (ii) Pig iron
(c) Blister copper                  (iii) Leaching with dilute NaCN solution
(d) Froth floatation method   (iv) Sulfide ores
Choose the correct answer from the options given below:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 43


Which one of the following metal complexes is most stable?

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 44



Consider the above reaction sequence, Product "A" and Product "B" formed respectively are:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 45


What is the major product "P" of the following reaction?

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 46



Maleic anhydride
Maleic anhydride can be prepared by:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 47



Consider the above reaction, the Product "P" is:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 48


A reaction of benzonitrile with one equivalent CH$$_3$$MgBr followed by hydrolysis produces a yellow liquid "P". The compound "P" will give positive _________ test.

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 49


A biodegradable polyamide can be made from:

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 50


Which one of the following is correct structure for cytosine?

NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 51


The number of significant figures in 0.00340 is _________

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 52


An accelerated electron has a speed of $$5 \times 10^6$$ ms$$^{-1}$$ with an uncertainty of 0.02%. The uncertainty in finding its location while in motion is $$x \times 10^{-9}$$ m. The value of $$x$$ is _________. (Nearest integer)
[Use mass of electron = $$9.1 \times 10^{-31}$$ kg, h = $$6.63 \times 10^{-34}$$ Js, $$\pi$$ = 3.14]

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 53


An LPG cylinder contains gas at a pressure of 300 kPa at 27°C. The cylinder can withstand the pressure of $$1.2 \times 10^6$$ Pa. The room in which the cylinder is kept catches fire. The minimum temperature at which the bursting of cylinder will take place is _________ °C. (Nearest integer)

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 54


A system does 200 J of work and at the same time absorbs 150 J of heat. The magnitude of the change in internal energy is _________J. (Nearest integer)

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 55


Assuming that Ba(OH)$$_2$$ is completely ionised in aqueous solution under the given conditions the concentration of H$$_3$$O$$^+$$ ions in 0.005M aqueous solution of Ba(OH)$$_2$$ at 298 K is _________ $$\times 10^{-12}$$ mol L$$^{-1}$$. (Nearest integer)

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 56


0.8 g of an organic compound was analysed by Kjeldahl's method for the estimation of nitrogen. If the percentage of nitrogen in the compound was found to be 42%, then _________ mL of 1M H$$_2$$SO$$_4$$ would have been neutralized by the ammonia evolved during the analysis.

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 57



Consider the above chemical reaction. The total number of stereoisomers possible for Product "P" is _________
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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 58


When 3.00 g of a substance X' is dissolved in 100 g of CCl$$_4$$, it raises the boiling point by 0.60 K. The molar mass of the substance 'X' is _________ g mol$$^{-1}$$. (Nearest integer).
[Given K$$_b$$ for CCl$$_4$$ is 5.0 K kg mol$$^{-1}$$]

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 59


For a chemical reaction A $$\rightarrow$$ B, it was found that concentration of B is increased by 0.2 mol L$$^{-1}$$ in 30 min. The average rate of the reaction is _________ $$\times 10^{-1}$$ mol L$$^{-1}$$ h$$^{-1}$$. (in nearest integer)

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NTA JEE Main 25th July 2021 Shift 2 - Chemistry - Question 60


Number of electrons present in 4f orbital of Ho$$^{3+}$$ ion is _________ (Given Atomic No. of Ho = 67)

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